journal article·2009-05-18

Supramolecular Self‐Assembled Dendritic Nonlinear Optical Chromophores: Fine‐Tuning of Arene–Perfluoroarene Interactions for Ultralarge Electro‐Optic Activity and Enhanced Thermal Stability

Xing‐Hua Zhou, Jingdong Luo, Su Huang, Tae‐Dong Kim, Zhengwei Shi, Yen‐Ju Cheng, Sei‐Hum Jang, Daniel B. Knorr, René M. Overney, Alex K.‐Y. Jen

Advanced Materials· Volume 21· Issue 19
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Abstract

Unprecedented electro-optic (EO) activity and excellent alignment stability at 85 °C are demonstrated through rational design of a new series of dendronized polyenic chromophores capable of supramolecular self-assembly directed by fine-tuned arene–perfluoroarene interactions. Analysis of the EO properties showed exceptional poling efficiency for these molecular glasses at high chromophore number density.
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Research context

OpenAlex topics: Nonlinear Optical Materials Research · Luminescence and Fluorescent Materials · Liquid Crystal Research Advancements

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