Tough, Recyclable, and Degradable Elastomers for Potential Biomedical Applications

Abstract Elastomers have many industrial, medical and commercial applications, however, their huge demand raises an important question of how to dispose of the out‐of‐service elastomers. Ideal elastomers that are concurrently tough, recyclable, and degradable are in urgent need, but their preparation remains a rigorous challenge. Herein, a polycaprolactone (PCL) based polyurethane elastomer is designed and prepared to meet this demand. Owing to the presence of dynamic coordination bond and the occurrence of strain‐induced crystallization, the obtained elastomer exhibits a high toughness of ≈372 MJ m⁻³ and an unprecedented fracture energy of ≈646 kJ m⁻², which is much higher than natural rubber (≈50 MJ m⁻³ for toughness and ≈10 kJ m⁻² for fracture energy). In addition, the elastomer can be recycled at least three times using solvent without losing its mechanical properties and can be degraded by lipase in ≈2 months. Finally, biological experiments demonstrate that the elastomer possesses good biocompatibility and can facilitate wound healing in mice when used as sutures. It is believed that the obtained elastomer meets the requirements for next‐generation elastomers and is expected to be used in emerging fields such as biomedicine, flexible electronics, robotics and beyond.