Robust Fe₃Mo₃C Supported IrMn Clusters as Highly Efficient Bifunctional Air Electrode for Metal–Air Battery

Abstract Catalysts at the air cathode for oxygen reduction and evolution reactions are central to the stability of rechargeable metal–air batteries, an issue that is gaining increasing interest in recent years. Herein, a highly durable and efficient carbide‐based bifunctional catalyst consisting of iron–molybdenum carbide (Fe₃Mo₃C) and IrMn nanoalloys is demonstratred. This carbide is chemically stable in alkaline media and over the potential range of an air cathode. More importantly, Fe₃Mo₃C is very active for oxygen reduction reaction (ORR) in alkaline media. Fe₃Mo₃C supported IrMn as a bifunictional catalysts exhibits superior catalytic performance than the state of the art ORR catalyst (Pt/C) and the oxygen evolution reaction catalyst (Ir/C). IrMn/Fe₃Mo₃C enables Zn–air batteries to achieve long‐term cycling performance over 200 h with high efficiency. The extraordinarily high performance of IrMn/Fe₃Mo₃C bifunictional catalyst provides a very promising alternative to the conventional Pt/C and Ir/C catalyst for an air cathode in alkaline electrolyte.