journal article·2016-12

A Novel Approach to Developing Biomimetic (“Nacre‐Like”) Metal‐Compliant‐Phase (Nickel–Alumina) Ceramics through Coextrusion

Ryan P. Wilkerson, Bernd Gludovatz, Jeremy Watts, Antoni P. Tomsia, Gregory E. Hilmas, Robert O. Ritchie

Advanced Materials· Volume 28· Issue 45
Publisher page

Abstract

Bioinspired “brick-and-mortar” alumina ceramics containing a nickel compliant phase are synthesized by coextrusion of alumina and nickel oxide. Results show that these structures are coarser yet exhibit exceptional resistance-curve behavior with a fracture toughness three or more times higher than that of alumina, consistent with significant extrinsic toughening, from crack bridging and “brick” pull-out, in the image of natural nacre. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Calcium Carbonate Crystallization and Inhibition · Bone Tissue Engineering Materials · Innovations in Concrete and Construction Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering University of California Berkeley CA 94720 USA

Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA

Department of Materials Science and Engineering Missouri University of Science and Technology Rolla MO 65409 USA

Funding

U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division

References (42)

Show source-provided references
1. 10.1038/nmat408910.1038/nmat4089 ↗
2. 10.1080/1478643041000168093510.1080/14786430410001680935 ↗
3. 10.1016/S0928-4931(00)00133-810.1016/S0928-4931(00)00133-8 ↗
4. 10.1038/nmat311510.1038/nmat3115 ↗
5. 10.1098/rspb.1988.005610.1098/rspb.1988.0056 ↗
6. 10.1046/j.1525-142x.2001.003002047.x10.1046/j.1525-142x.2001.003002047.x ↗
7. 10.1002/adma.20120271310.1002/adma.201202713 ↗
8. Intrinsic toughening mechanisms operate ahead of the crack tip to generate resistance to microstructural damage. The most prominent mechanism is that of plastic (or inelastic) deformation which provides a means of blunting the crack tip through the formation of plastic zones. Extrinsic toughening mechanisms conversely operate primarily in the wake of the crack tip to inhibit cracking by “shielding” the crack from the applied driving force. Whereas intrinsic toughening mechanisms are effective in inhibiting both the initiation and growth of cracks extrinsic mechanisms e.g. crack bridging and crack deflection are only effective in providing resistance to crack growth.
9. 10.1002/adma.20080332210.1002/adma.200803322 ↗
10. 10.1016/j.jmps.2006.07.00710.1016/j.jmps.2006.07.007 ↗
11. 10.1016/j.jmps.2012.03.00210.1016/j.jmps.2012.03.002 ↗
12. 10.1098/rsif.2013.101610.1098/rsif.2013.1016 ↗
13. 10.1016/j.jmps.2014.08.00810.1016/j.jmps.2014.08.008 ↗
14. 10.1038/ncomms752310.1038/ncomms7523 ↗
15. 10.1126/science.116486510.1126/science.1164865 ↗
16. 10.1126/science.114872610.1126/science.1148726 ↗
17. 10.1016/j.actamat.2009.03.00310.1016/j.actamat.2009.03.003 ↗
18. 10.1016/j.msec.2009.04.00110.1016/j.msec.2009.04.001 ↗
19. 10.1098/rsif.2009.033110.1098/rsif.2009.0331 ↗
20. 10.1038/nmat391510.1038/nmat3915 ↗
21. 10.1021/nn503755c10.1021/nn503755c ↗
22. 10.1002/adma.20150030310.1002/adma.201500303 ↗
23. 10.1016/j.actamat.2015.07.02210.1016/j.actamat.2015.07.022 ↗
24. 10.1002/adma.20150431310.1002/adma.201504313 ↗
25. 10.1002/adma.20160083910.1002/adma.201600839 ↗
26. 10.1002/adma.20150551110.1002/adma.201505511 ↗
27. 10.1021/acsnano.6b0175210.1021/acsnano.6b01752 ↗
28. 10.1007/s10853-006-0978-710.1007/s10853-006-0978-7 ↗
29. 10.1111/j.1551-2916.2008.02824.x10.1111/j.1551-2916.2008.02824.x ↗
30. 10.1016/j.ijrmhm.2005.04.01910.1016/j.ijrmhm.2005.04.019 ↗
31. 10.1111/j.1151-2916.1994.tb05400.x10.1111/j.1151-2916.1994.tb05400.x ↗
32. 10.1016/0921-5093(94)06525-X10.1016/0921-5093(94)06525-X ↗
33. 10.1111/j.1151-2916.1993.tb07756.x10.1111/j.1151-2916.1993.tb07756.x ↗
34. 10.1111/j.1151-2916.1993.tb07757.x10.1111/j.1151-2916.1993.tb07757.x ↗
35. 10.1111/j.1151-2916.1997.tb03148.x10.1111/j.1151-2916.1997.tb03148.x ↗
36. 10.1111/j.1151-2916.2001.tb00664.x10.1111/j.1151-2916.2001.tb00664.x ↗
37. 10.1038/nmeth.208910.1038/nmeth.2089 ↗
38. 10.1111/j.1551-2916.2005.00434.x10.1111/j.1551-2916.2005.00434.x ↗
39. 10.1007/BF0035288510.1007/BF00352885 ↗
40. 10.1016/j.msea.2003.08.12110.1016/j.msea.2003.08.121 ↗
41. 10.1111/j.1151-2916.2000.tb01368.x10.1111/j.1151-2916.2000.tb01368.x ↗
42. 10.1111/j.1151-2916.1998.tb02307.x10.1111/j.1151-2916.1998.tb02307.x ↗