Harvesting All Electrogenerated Excitons through Metal Assisted Delayed Fluorescent Materials

Highly efficient and stable palladium complexes that exhibit both phosphorescence and delayed fluorescence are developed. It is demonstrated that the emission from the two processes can be separately tuned through rational ligand modification. External quantum efficiencies over 20% are achieved and stable devices demonstrate an operational lifetime to 90% initial luminance estimated at over 20 000 h at 100 cd m−2. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.