journal article·2014-11

Ionic Liquid Enabled FeS2 for High‐Energy‐Density Lithium‐Ion Batteries

Tyler Evans, Daniela Molina Piper, Seul Cham Kim, Sang Sub Han, Vinay Bhat, Kyu Hwan Oh, Se‐Hee Lee

Advanced Materials· Volume 26· Issue 43
Publisher page

Abstract

High-energy-density FeS2 cathodes en-abled by a bis(trifluoromethanesulfonyl)imide (TFSI-) anion-based room temperature ionic liquid (RTIL) electrolyte are demonstrated. A TFSI-based ionic liquid (IL) significantly mitigates polysulfide dissolution, and therefore the parasitic redox shuttle mechanism, that plagues sulfur-based electrode chemistries. FeS2 stabilization with a TFSI(-) -based IL results in one of the highest energy density cathodes, 542 W h kg(-1) (normalized to cathode composite mass), reported to date.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced battery technologies research

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Affiliations

Department of Mechanical Engineering University of Colorado at Boulder Boulder CO 80309 USA

Department of Materials Science and Engineering Seoul National University Seoul 151–742 Korea

Boulder Ionics Corporation 18300 West Highway 72 Arvada CO 80007 USA

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