journal article·2016-05Open access

Alkaline Anion‐Exchange Membranes Containing Mobile Ion Shuttles

Xiaolin Ge, Yubin He, Michael D. Guiver, Liang Wu, Jin Ran, Zhengjin Yang, Tongwen Xu

Advanced Materials· Volume 28· Issue 18

Abstract

A new class of alkaline anion-exchange membranes containing mobile ion shuttles is developed. It is achieved by threading ionic linear guests into poly(crown ether) hosts via host–guest molecular interaction. The thermal- and pH-triggered shuttling of ionic linear guests remarkably increases the solvation-shell fluctuations in inactive hydrated hydroxide ion complexes (OH−(H2O)4) and accelerates the OH− transport. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Research context

OpenAlex topics: Fuel Cells and Related Materials · Membrane-based Ion Separation Techniques · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CAS Key Laboratory of Soft Matter Chemistry Collaborative Innovation Center of Chemistry for Energy Materials School of Chemistry and Materials Science University of Science and Technology of China Hefei 230026 P. R. China

State Key Laboratory of Engines School of Mechanical Engineering Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) Tianjin University 92 Weijin Road Tianjin 300072 P. R. China

Funding

National Basic Research Program of China · National Natural Science Foundation of China

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