journal article·2021-11

Harnessing the Volume Expansion of MoS3 Anode by Structure Engineering to Achieve High Performance Beyond Lithium‐Based Rechargeable Batteries

Mingze Ma, Shipeng Zhang, Lifeng Wang, Yu Yao, Ruiwen Shao, Lin Shen, Lai Yu, Junyi Dai, Yu Jiang, Xiaolong Cheng, Ying Wu, Xiaojun Wu, Xiayin Yao, Qiaobao Zhang, Yan Yu

Advanced Materials· Volume 33· Issue 45
Publisher page

Abstract

Abstract Beyond‐lithium‐ion storage devices are promising alternatives to lithium‐ion storage devices for low‐cost and large‐scale applications. Nowadays, the most of high‐capacity electrodes are crystal materials. However, these crystal materials with intrinsic anisotropy feature generally suffer from lattice strain and structure pulverization during the electrochemical process. Herein, a 2D heterostructure of amorphous molybdenum sulfide (MoS3) on reduced graphene surface (denoted as MoS3‐on‐rGO), which exhibits low strain and fast reaction kinetics for beyond‐lithium‐ions (Na+, K+, Zn2+) storage is demonstrated. Benefiting from the low volume expansion and small sodiation strain of the MoS3‐on‐rGO, it displays ultralong cycling performance of 40 000 cycles at 10 A g−1 for sodium‐ion batteries. Furthermore, the as‐constructed 2D heterostructure also delivers superior electrochemical performance when used in Na+ full batteries, solid‐state sodium batteries, K+ batteries, Zn2+ batteries and hybrid supercapacitors, demonstrating its excellent application prospect.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Hefei National Laboratory for Physical Sciences at the Microscale Department of Materials Science and Engineering National Synchrotron Radiation Laboratory CAS Key Laboratory of Materials for Energy Conversion University of Science and Technology of China Hefei Anhui 230026 China

State Key Lab Incubation Base of Photoelectric Technology and Functional Materials International Collaborative Center on Photoelectric Technology and Nano Functional Materials Institute of Photonics and Photon‐Technology Northwest University Xi'an 710069 China

Beijing Advanced Innovation Center for Intelligent Robots and Systems and Institute of Convergence in Medicine and Engineering Beijing Institute of Technology Beijing 100081 China

Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo 315201 China

Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049 China

Department of Materials Science and Engineering College of Materials Xiamen University Xiamen Fujian 361005 China

Funding

National Natural Science Foundation of China · National Synchrotron Radiation Laboratory · Fundamental Research Funds for the Central Universities · National Postdoctoral Program for Innovative Talents · China Postdoctoral Science Foundation

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