Formation of CX Bonds in CO₂ Chemical Fixation Catalyzed by Metal−Organic Frameworks

Abstract Transformation of CO₂ based on metal−organic framework (MOF) catalysts is becoming a hot research topic, not only because it will help to reduce greenhouse gas emission, but also because it will allow for the production of valuable chemicals. In addition, a large number of impressive products have been synthesized by utilizing CO₂. In fact, it is the formation of new covalent bonds between CO₂ and substrate molecules that successfully result in CO₂ solidly inserting into the products, and only four types of new CX bonds, including CH, CC, CN, and CO bonds, are observed in this exploration. An overview of recent progress in constructing CX bonds for CO₂ conversion catalyzed by various MOF catalysts is provided. The catalytic mechanism of generating different CX bonds is further discussed according to both structural features of MOFs and the interactions among CO₂, substrates, as well as MOFs. The future opportunities and challenges in this field are also tentatively covered.