Single‐Site Au^I Catalyst for Silane Oxidation with Water

Abstract Single‐site Au anchored on mpg‐C₃N₄ (519 ppm Au loading) is developed as a highly active, selective, and stable catalyst for the oxidation of silanes with water with a turnover frequency as high as 50 200 h⁻¹, far exceeding most known catalysts based on total gold content. Other hydrosilanes bearing unsaturated functional groups also lead to corresponding silanols under mild reaction conditions without formation of any side products in good or excellent yields. The spherical aberration correction electron microscopy and extended X‐ray absorption fine structure measurements both confirm the atomic dispersion of Au atoms stabilized by mpg‐C₃N₄. The coordination of the catalytically active Au^I by three nitrogen or carbon atoms in the tri‐s‐triazine repeating units not only prevents the Au atoms from aggregation, but also renders the surface Au^I highly active, which is completely different than homogeneous Au^I species.