DataVXAdvanced MaterialsPaper
journal article·2019-12

Construction of Hierarchical Metal–Organic Frameworks by Competitive Coordination Strategy for Highly Efficient CO2 Conversion

Gang‐Gang Chang, Xiao‐Chen Ma, Yue‐Xing Zhang, Li‐Ying Wang, Ge Tian, Jia‐Wen Liu, Jian Wu, Zhi‐Yi Hu, Xiao‐Yu Yang, Banglin Chen

Advanced Materials· Volume 31· Issue 52
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Source abstract

Abstract

Abstract Hierarchical porosity and functionalization help to fully make use of metal–organic frameworks (MOFs) for their diverse applications. Herein, a simple strategy is reported to construct hierarchically porous MOFs through a competitive coordination method using tetrafluoroborate (M(BF4)x, where M is metal site) as both functional sites and etching agents. The resulting MOFs have in situ formed defect‐mesopores and functional sites without sacrificing their structure stability. The formation mechanism of the defect‐mesopores is elucidated by a combination of experimental and first‐principles calculation method, indicating the general feasibility of this new approach. Compared with the original microporous counterparts, the new hierarchical MOFs exhibit superior adsorption for the bulky dye molecules and catalytic performance for the CO2 conversion attributed to their specific hierarchical pore structures.
Source: crossref · Quality: baseline

Research context

Catalysis & surfaces

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Carbon dioxide utilization in catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry Chemical Engineering and Life Science State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan Hubei 430070 China

Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules College of Chemistry and Chemical Engineering Hubei University Wuhan Hubei 430062 China

State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics Wuhan Institute of Physics and Mathematics The Chinese Academy of Sciences Wuhan Hubei 430071 China

Department of Chemistry University of Texas at San Antonio One UTSA Circle San Antonio TX 78249‐0698 USA

Funding

National Natural Science Foundation of China · National Basic Research Program of China · Natural Science Foundation of Hubei Province

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