Nanoparticle Self‐Assembly of Hierarchically Ordered Microcapsule Structures
Source abstract
Abstract
Microcapsules with multilayer-thick shells are synthesized by depositing negatively charged nanoparticles around cationic polyamine aggregates crosslinked by multivalent counteranions (see Figure and inside cover). Unique among hollow-sphere preparative routes, this rapid and green synthesis leads to a robust organic/inorganic hybrid structure, applies to a wide spectrum of colloidal species, and permits the non-destructive encapsulation of water-soluble compounds.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Polymer Surface Interaction Studies · Pickering emulsions and particle stabilization · Surfactants and Colloidal Systems
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (38)
Show source-provided references
1. 10.1038/382313a010.1038/382313a0 ↗
2. 10.1073/pnas.08206589910.1073/pnas.082065899 ↗
3. 10.1021/ar020083j10.1021/ar020083j ↗
4. 10.1002/anie.20030170410.1002/anie.200301704 ↗
5. 10.1021/la960319q10.1021/la960319q ↗
6. 10.1126/science.270.5240.133510.1126/science.270.5240.1335 ↗
7. 10.1038/nature0120810.1038/nature01208 ↗
8. 10.1002/adma.20030580410.1002/adma.200305804 ↗
9. 10.1021/ja038336710.1021/ja0383367 ↗
10. 10.1103/PhysRevLett.89.24830310.1103/PhysRevLett.89.248303 ↗
11. 10.1038/414735a10.1038/414735a ↗
12. 10.1002/adma.20030481810.1002/adma.200304818 ↗
13. 10.1038/nmat77510.1038/nmat775 ↗
14. 10.1038/nature0191510.1038/nature01915 ↗
15. 10.1038/nature0170210.1038/nature01702 ↗
16. 10.1038/nature0208710.1038/nature02087 ↗
17. 10.1021/ja026328510.1021/ja0263285 ↗
18. 10.1002/1521-4095(20020816)14:16<1126::AID-ADMA1126>3.0.CO;2-A10.1002/1521-4095(20020816)14:16<1126::AID-ADMA1126>3.0.CO;2-A ↗
19. 10.1038/382607a010.1038/382607a0 ↗
20. 10.1021/ja000477a10.1021/ja000477a ↗
21. 10.1126/science.107208610.1126/science.1072086 ↗
22. 10.1002/adma.20039011510.1002/adma.200390115 ↗
23. 10.1038/3500803710.1038/35008037 ↗
24. 10.1021/nl020244c10.1021/nl020244c ↗
25. Mater. Res. Soc. Symp. Proc.(Eds: D. L. Wilcox Sr. M. Berg T. Bernat D. Kellerman J. K. Cochran Jr.) Materials Research Society Pittsburgh PA1995 Vol. 372.
26. 10.1002/(SICI)1521-3765(20000204)6:3<413::AID-CHEM413>3.0.CO;2-910.1002/(SICI)1521-3765(20000204)6:3<413::AID-CHEM413>3.0.CO;2-9 ↗
27. 10.1021/ja027960110.1021/ja0279601 ↗
28. 10.1021/ja038953v10.1021/ja038953v ↗
29. 10.1126/science.282.5391.111110.1126/science.282.5391.1111 ↗
30. 10.1126/science.107622110.1126/science.1076221 ↗
31. 10.1002/anie.20035221210.1002/anie.200352212 ↗
32. 10.1039/b302056h10.1039/b302056h ↗
33. 10.1002/jmr.65710.1002/jmr.657 ↗
34. 10.1021/je010142o10.1021/je010142o ↗
35. K. S. Schmitz Macroions in Solution and Colloidal Suspension VCH Weinheim Germany1993. Counterion condensation occurs to neutralize a percentage of the ionizable side groups of the repeat units such that the average distance between the charged groups (lB Bjerrum length) is sufficiently large to reduce the electrostatic interaction potential between the like‐charged groups down to thermal energy levels (e2/εlB ∼ kT;e: electron charge ε: dielectric constant;k: Boltzmann's constant;T: temperature).
36. R. J. Hunter Foundations of Colloid Science 3rd ed. Oxford University Press New York2001.
37. 10.1016/S1389-0344(01)00088-010.1016/S1389-0344(01)00088-0 ↗
38. 10.1002/1521-3773(20021018)41:20<3789::AID-ANIE3789>3.0.CO;2-D10.1002/1521-3773(20021018)41:20<3789::AID-ANIE3789>3.0.CO;2-D ↗