journal article·2000-06

Influence of Aromatic Groups Incorporated in Long-Chain Alkanethiol Self-Assembled Monolayers on Gold

F. Buckel, F. Effenberger, C. Yan, A. Gölzhäuser, M. Grunze

Advanced Materials· Volume 12· Issue 12
Publisher page

Abstract

The effect of aromatic rings on the orientation and packing of SAMs (self-assembled monolayers) on gold is investigated in this paper. Terminally aryl-substituted eicosanethiols and eicosylthiophenols as well as the oligo(arylalkyl) thiol shown in the Figure are examined. It is shown that the tilt angle may be influenced by the incorporation of aryl groups and densely packed, highly ordered SAMs are obtained.
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Research context

OpenAlex topics: Molecular Junctions and Nanostructures · Adsorption, diffusion, and thermodynamic properties of materials

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