The Direct Writing of Plasmonic Gold Nanostructures by Electron‐Beam‐Induced Deposition
Source abstract
Abstract
Various nanostructures are directly written by electron-beam-induced deposition using dimethyl-gold(III)-acetylacetonate as the precursor gas. After purification, their potential applications include plasmonic devices and metamaterials. Carbon contamination of the as-written structures can be completely removed by low-temperature ozone treatment, leaving polycrystalline pure gold structures (see figure). This treatment reduces the size of the nanostructures but does not substantially alter their functional shape. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Research context
OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Advanced Electron Microscopy Techniques and Applications · Plasmonic and Surface Plasmon Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (27)
Show source-provided references
1. 10.1117/12.61714210.1117/12.617142 ↗
2. 10.1116/1.295572810.1116/1.2955728 ↗
3. 10.1088/0957-4484/17/15/02810.1088/0957-4484/17/15/028 ↗
4. 10.1088/0957-4484/18/46/46560210.1088/0957-4484/18/46/465602 ↗
5. 10.1002/smll.20070113310.1002/smll.200701133 ↗
6. 10.1088/0957-4484/20/37/37200110.1088/0957-4484/20/37/372001 ↗
7. 10.1021/nl034528o10.1021/nl034528o ↗
8. 10.1116/1.131969010.1116/1.1319690 ↗
9. 10.1016/S1369-7021(09)70071-910.1016/S1369-7021(09)70071-9 ↗
10. 10.1126/science.111484910.1126/science.1114849 ↗
11. 10.1088/0957-4484/19/48/48530210.1088/0957-4484/19/48/485302 ↗
12. 10.1088/0957-4484/18/26/26530810.1088/0957-4484/18/26/265308 ↗
13. 10.1116/1.205067210.1116/1.2050672 ↗
14. 10.1103/PhysRevLett.102.02390110.1103/PhysRevLett.102.023901 ↗
15. 10.1063/1.308687310.1063/1.3086873 ↗
16. 10.1126/science.117703110.1126/science.1177031 ↗
17. The heavier gold atoms appear darker in the bright field contrast mode of the TEM than the much lighter carbon atoms.
18. 10.1143/JJAP.33.709910.1143/JJAP.33.7099 ↗
19. 10.1016/j.mee.2005.01.00610.1016/j.mee.2005.01.006 ↗
20. 10.1063/1.151718010.1063/1.1517180 ↗
21. 10.1103/PhysRevA.13.228710.1103/PhysRevA.13.2287 ↗
22. 10.1016/0304-5102(83)80036-410.1016/0304-5102(83)80036-4 ↗
23. 10.1103/PhysRevB.61.1608410.1103/PhysRevB.61.16084 ↗
24. This is in agreement with an estimate based on the atomic percentage (14–28 at%) of gold in the original deposits. Using the molar volumes of gold and carbon the as‐deposited structures contain 27– 54 vol% of gold.
25. 10.1038/nmat77410.1038/nmat774 ↗
26. 10.1063/1.278660010.1063/1.2786600 ↗
27. The use of molybdenum grids instead of the standard copper grids was required due to their stability in the presence of the strongly oxidizing ozone.