In‐situ Reconstruction of Catalyst in Electrocatalysis

Abstract Reconstruction of catalysts is now well recognized as a common phenomenon in electrocatalysis. As the reconstructed structure may promote or hamper the electrochemical performance, how to achieve the designed active surface for highly enhanced catalytic activity through the reconstruction needs to be carefully investigated. In this review, the genesis and electrochemical effects of reconstruction in various electrochemical catalytic processes, such as hydrogen evolution reaction (HER), oxygen evolution reaction (OER), carbon dioxide reduction reaction (CO ₂ RR), and nitrate reduction reaction (NO ₃ RR) are first described. Then, the strategies for optimizing the reconstruction, such as valence states control, active phase retention, phase evolution engineering, and surface poisoning prevention are comprehensively discussed. Finally, the general rules of reconstruction optimization are summarized and give perspectives for future study. It is believed that the review shall provide deep insights into electrocatalytic mechanisms and guide the design of pre‐catalysts with highly improved activity.