journal article·2017-05

Architecture of β‐Graphdiyne‐Containing Thin Film Using Modified Glaser–Hay Coupling Reaction for Enhanced Photocatalytic Property of TiO2

Jiaqiang Li, Ziqian Xie, Yan Xiong, Zhenzhu Li, Qunxing Huang, Shuqing Zhang, Jingyuan Zhou, Rong Liu, Xin Gao, Changguo Chen, Lianming Tong, Jin Zhang, Zhongfan Liu

Advanced Materials· Volume 29· Issue 19
Publisher page

Abstract

β‐Graphdiyne (β‐GDY) is a member of 2D graphyne family with zero band gap, and is a promising material with potential applications in energy storage, organic electronics, etc. However, the synthesis of β‐GDY has not been realized yet, and the measurement of its intrinsic properties remains elusive. In this work, β‐GDY‐containing thin film is successfully synthesized on copper foil using modified Glaser–Hay coupling reaction with tetraethynylethene as precursor. The as‐grown carbon film has a smooth surface and is continuous and uniform. Electrical measurements reveal the conductivity of 3.47 × 10−6 S m−1 and the work function of 5.22 eV. TiO2@β‐GDY nanocomposite is then prepared and presented with an enhancement of photocatalytic ability compared to pure TiO2.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Advanced Memory and Neural Computing · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering Chongqing University Chongqing 401331 P. R. China

Center for Nanochemistry Beijing Science and Engineering Center for Nanocarbons Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular Engineering Peking University Beijing 100871 P. R. China

Academy for Advanced Interdisciplinary Studies Peking University Beijing 100871 P. R. China

The National Center for Nanoscience and Technology Beijing 100190 P. R. China

Funding

National Natural Science Foundation of China · Ministry of Science and Technology of the People's Republic of China

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