Non‐Electrode Components for Rechargeable Aqueous Zinc Batteries: Electrolytes, Solid‐Electrolyte‐Interphase, Current Collectors, Binders, and Separators

Abstract Rechargeable aqueous zinc batteries (AZBs) are one of the promising options for large‐scale electrical energy storage owing to their safety, affordability and environmental friendliness. During the past decade, there have been remarkable advancements in the AZBs technology, which are achieved through intensive efforts not only in the area of electrode materials but also in the fundamental understandings of non‐electrode components such as electrolytes, solid electrolyte interphase (SEI), current collectors, binders, and separators. In particular, the breakthroughs in the non‐electrode components should not be underestimated in having enabled the AZBs to attain a higher energy and power density beyond that of the conventional AZBs, proving their critical role. In this article, the recent research progress is comprehensively reviewed with respect to non‐electrode components in AZBs, covering the new‐type of electrolytes that have been introduced, attempts for the tailoring of SEI, and the design efforts for multi‐functional current collectors, binders and separators, along with the remaining challenges associated with these non‐electrode components. Finally, perspectives are discussed toward future research directions in this field. This extensive overview on the non‐electrode components is expected to guide and spur further development of high‐performance AZBs.