journal article·2005-08-04

A Stable and Highly Active Hybrid Mesoporous Solid Acid Catalyst

K. Nakajima, I. Tomita, M. Hara, S. Hayashi, K. Domen, J. N. Kondo

Advanced Materials· Volume 17· Issue 15
Publisher page

Abstract

Ethenylene groups within the silicate framework of hybrid mesoporous ethenylene-silica (HME) are successfully modified via a two-step chemical modification process (see Figure) to produce a sulfonic acid-functionalized hybrid mesoporous solid acid catalyst. The material exhibits high activity for various acid-catalyzed reactions and can be used repeatedly without deactivation. The Diels–Alder modification described can be extended to the creation of other functional materials.
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Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Chemical Synthesis and Reactions · Polyoxometalates: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (26)

Show source-provided references
1. 10.1038/359710a010.1038/359710a0 ↗
2. 10.1126/science.279.5350.54810.1126/science.279.5350.548 ↗
3. 10.1021/ja991665810.1021/ja9916658 ↗
4. 10.1038/4722910.1038/47229 ↗
5. 10.1039/a908252b10.1039/a908252b ↗
6. 10.1021/cm990393510.1021/cm9903935 ↗
7. 10.1038/416304a10.1038/416304a ↗
8. 10.1039/b103960c10.1039/b103960c ↗
9. 10.1021/cm034898d10.1021/cm034898d ↗
10. 10.1021/cm035235z10.1021/cm035235z ↗
11. 10.1021/cr010334m10.1021/cr010334m ↗
12. 10.1021/cr010368u10.1021/cr010368u ↗
13. 10.1126/science.276.5314.92310.1126/science.276.5314.923 ↗
14. 10.1039/a704320a10.1039/a704320a ↗
15. 10.1039/a707462j10.1039/a707462j ↗
16. 10.1021/cm970713p10.1021/cm970713p ↗
17. 10.1006/jcat.1998.235310.1006/jcat.1998.2353 ↗
18. 10.1021/cm001030410.1021/cm0010304 ↗
19. 10.1021/jp020131h10.1021/jp020131h ↗
20. 10.1021/ja026799r10.1021/ja026799r ↗
21. 10.1039/b110598c10.1039/b110598c ↗
22. 10.1021/ja034594s10.1021/ja034594s ↗
23. 10.1039/B316467E10.1039/B316467E ↗
24. 10.1016/j.jcat.2004.01.02510.1016/j.jcat.2004.01.025 ↗
25. 10.1021/ar50147a00210.1021/ar50147a002 ↗
26. 10.1016/j.jcat.2004.09.00710.1016/j.jcat.2004.09.007 ↗