The Dark Side of Lead-Free Metal Halide Nanocrystals: Substituent-Modulated Photocatalytic Activity in Benzyl Bromide Reduction
Source abstract
Abstract
High Resolution Image Download MS PowerPoint Slide We illustrate here the high photocatalytic activity of sustainable lead-free metal halide nanocrystals (NCs), namely, Cs 3 Sb 2 Br 9 NCs, in the reduction of p -substituted benzyl bromides in the absence of a cocatalyst. The electronic properties of the benzyl bromide substituents and the substrate affinity to the NC surface determine the selectivity in C–C homocoupling under visible light irradiation. This photocatalyst can be reused for at least three cycles and preserves its good performance with a turnover number of ca. 105,000.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Perovskite Materials and Applications · Advanced Photocatalysis Techniques · Quantum Dots Synthesis And Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Molecular Science, University of Valencia, c/Cat. José Beltrán 2, Paterna, 46980 Valencia, Spain
Nanochemistry, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy
Materials Characterization Facility, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy
Funding
Generalitat Valenciana · Ministerio de Ciencia, Innovaci?n y Universidades · Agencia Estatal de Investigaci?n · Ministerio de Ciencia e Innovaci?n · European Regional Development Fund
References (67)
Show source-provided references
1. 10.3390/w1403037110.3390/w14030371 ↗
2. 10.1021/acs.chemrev.6b0005710.1021/acs.chemrev.6b00057 ↗
3. 10.1021/cr300503r10.1021/cr300503r ↗
4. 10.1246/bcsj.79.66310.1246/bcsj.79.663 ↗
5. 10.1021/acsenergylett.8b0015210.1021/acsenergylett.8b00152 ↗
6. 10.26599/NRE.2022.912000610.26599/NRE.2022.9120006 ↗
7. 10.1021/acssuschemeng.0c0517910.1021/acssuschemeng.0c05179 ↗
8. 10.1021/acs.chemrev.8b0053910.1021/acs.chemrev.8b00539 ↗
9. 10.1002/adma.20130517210.1002/adma.201305172 ↗
10. 10.1002/adma.20130628110.1002/adma.201306281 ↗
11. 10.1126/science.124398210.1126/science.1243982 ↗
12. 10.1021/acsenergylett.9b0271410.1021/acsenergylett.9b02714 ↗
13. 10.1021/acs.nanolett.7b0200310.1021/acs.nanolett.7b02003 ↗
14. 10.1021/acsenergylett.9b0257310.1021/acsenergylett.9b02573 ↗
15. 10.1021/acsaem.2c0268010.1021/acsaem.2c02680 ↗
16. 10.1002/ejic.20180007810.1002/ejic.201800078 ↗
17. 10.1002/chem.20170223710.1002/chem.201702237 ↗
18. 10.1021/acsenergylett.0c0005810.1021/acsenergylett.0c00058 ↗
19. 10.1021/acsenergylett.8b0013110.1021/acsenergylett.8b00131 ↗
20. 10.1021/acsenergylett.8b0169810.1021/acsenergylett.8b01698 ↗
21. 10.1021/acsami.1c2471010.1021/acsami.1c24710 ↗
22. 10.1038/s41467-019-10634-x10.1038/s41467-019-10634-x ↗
23. 10.1021/jacs.8b0872010.1021/jacs.8b08720 ↗
24. 10.1039/D0CC01339K10.1039/D0CC01339K ↗
25. 10.1002/chem.20160351710.1002/chem.201603517 ↗
26. 10.1038/nrd206010.1038/nrd2060 ↗
27. 10.1039/b306797c10.1039/b306797c ↗
28. 10.1039/C9NR07722G10.1039/C9NR07722G ↗
29. 10.1002/cssc.20190071610.1002/cssc.201900716 ↗
30. 10.1021/acsenergylett.0c0003910.1021/acsenergylett.0c00039 ↗
31. 10.1007/s10853-018-3162-y10.1007/s10853-018-3162-y ↗
32. 10.1021/acsaem.2c0059110.1021/acsaem.2c00591 ↗
33. 10.1016/j.xcrp.2021.10065610.1016/j.xcrp.2021.100656 ↗
34. 10.1002/anie.20191503410.1002/anie.201915034 ↗
35. 10.1002/solr.20210055910.1002/solr.202100559 ↗
36. 10.1016/j.jcat.2022.02.02310.1016/j.jcat.2022.02.023 ↗
37. 10.1016/j.ces.2021.11698310.1016/j.ces.2021.116983 ↗
38. 10.1002/anie.20200549510.1002/anie.202005495 ↗
39. 10.1002/smll.20210600110.1002/smll.202106001 ↗
40. 10.1021/acsenergylett.1c0166210.1021/acsenergylett.1c01662 ↗
41. 10.1021/acsenergylett.1c0078910.1021/acsenergylett.1c00789 ↗
42. 10.1021/acs.inorgchem.9b0189310.1021/acs.inorgchem.9b01893 ↗
43. 10.1021/acsnano.7b0468310.1021/acsnano.7b04683 ↗
44. 10.4236/wjnse.2012.2302010.4236/wjnse.2012.23020 ↗
45. 10.1021/la025827g10.1021/la025827g ↗
46. 10.1021/la049764910.1021/la0497649 ↗
47. 10.1038/s41467-019-13951-310.1038/s41467-019-13951-3 ↗
48. Casadevall C. · 2022 · 1419 · 14510.1021/bk-2022-1419.ch009 ↗
49. 10.1126/science.756992210.1126/science.7569922 ↗
50. 10.1002/solr.20210026510.1002/solr.202100265 ↗
51. 10.1021/cs300270d10.1021/cs300270d ↗
52. 10.1021/acscatal.6b0283210.1021/acscatal.6b02832 ↗
53. 10.1039/C8SC04188A10.1039/C8SC04188A ↗
54. 10.1016/j.xcrp.2022.10088910.1016/j.xcrp.2022.100889 ↗
55. 10.1039/D1SC04305F10.1039/D1SC04305F ↗
56. 10.1021/acs.jpclett.9b0229410.1021/acs.jpclett.9b02294 ↗
57. Hansch C. H. · 1979
58. 10.1002/kin.2089010.1002/kin.20890 ↗
59. 10.1021/acs.chemrev.5b0048410.1021/acs.chemrev.5b00484 ↗
60. 10.1021/acsami.7b0848810.1021/acsami.7b08488 ↗
61. 10.1021/acsenergylett.8b0175410.1021/acsenergylett.8b01754 ↗
62. 10.1021/acscatal.1c0010210.1021/acscatal.1c00102 ↗
63. 10.1002/chem.20130057710.1002/chem.201300577 ↗
64. 10.1039/b110169m10.1039/b110169m ↗
65. 10.1021/ja00390a03510.1021/ja00390a035 ↗
66. 10.1039/C4NR06371F10.1039/C4NR06371F ↗
67. 10.1038/srep0066210.1038/srep00662 ↗