journal article·2013-11

Moderating Black Powder Chemistry for the Synthesis of Doped and Highly Porous Graphene Nanoplatelets and Their Use in Electrocatalysis

Xiaofeng Liu, Markus Antonietti

Advanced Materials· Volume 25· Issue 43
Publisher page

Abstract

Inspired by black powder explosion, a mixture of sugar and nitrate is diluted with inert molten salt, such that their rapid reaction is moderated, allowing capturing of the intermediacy product: highly porous N-doped graphene nanoplates. The methodology is extended to S-doped porous carbon sheets by replacing the nitrate with sulfate. These MS-derived carbons show promising performances towards electrocatalysis and capacitive energy storage.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Electrocatalysts for Energy Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Colloid Chemistry Max‐Planck Institute of Colloids and Interfaces, Research Campus Golm D‐14424 Potsdam Germany

Funding

Max Planck Society, an ERC Excellence Grant, and the Alexander von Humboldt foundation

References (58)

Show source-provided references
1. 10.1038/nature1145810.1038/nature11458 ↗
2. 10.1038/nnano.2009.5810.1038/nnano.2009.58 ↗
3. 10.1038/nature0921110.1038/nature09211 ↗
4. 10.1002/anie.20120595510.1002/anie.201205955 ↗
5. 10.1002/adma.20120171510.1002/adma.201201715 ↗
6. 10.1002/anie.20070204610.1002/anie.200702046 ↗
7. 10.1039/c2jm34066f10.1039/c2jm34066f ↗
8. 10.1016/j.colsurfa.2004.04.00710.1016/j.colsurfa.2004.04.007 ↗
9. 10.1126/science.117033510.1126/science.1170335 ↗
10. 10.1126/science.116804910.1126/science.1168049 ↗
11. 10.1103/PhysRevB.77.16542710.1103/PhysRevB.77.165427 ↗
12. 10.1002/adma.20090096510.1002/adma.200900965 ↗
13. 10.1021/ja900686d10.1021/ja900686d ↗
14. 10.1002/adma.20120246110.1002/adma.201202461 ↗
15. 10.1021/nn302147s10.1021/nn302147s ↗
16. 10.1002/adma.20120016410.1002/adma.201200164 ↗
17. 10.1002/adfm.20120164310.1002/adfm.201201643 ↗
18. 10.1039/c1gc15349h10.1039/c1gc15349h ↗
19. 10.1039/c1cc12272j10.1039/c1cc12272j ↗
20. 10.1002/adfm.20060123010.1002/adfm.200601230 ↗
21. 10.1039/c2cc35112a10.1039/c2cc35112a ↗
22. 10.1021/nn203393d10.1021/nn203393d ↗
23. 10.1002/anie.20120655410.1002/anie.201206554 ↗
24. 10.1002/adfm.20120018610.1002/adfm.201200186 ↗
25. Kelly J. · 2005
26. Cocroft W. · 2000
27. 10.1021/ja01459a01210.1021/ja01459a012 ↗
28. The ratio of LiNO3(L) K2SO4(K) and Na2S2O3(N) to glucose (G) should be lower than 1.1 1.5 and 2.5 respectively; otherwise there is no carbon yield. To balance doping level and sample yield in the text the samples shown in Figures 1 2 and 3 were synthesized at L/G = 1 (N‐doped) and K/G = 1 and N/G = 2 (S‐doped) respectively.
29. 10.1002/1521-3765(20020301)8:5<1151::AID-CHEM1151>3.0.CO;2-#10.1002/1521-3765(20020301)8:5<1151::AID-CHEM1151>3.0.CO;2-# ↗
30. 10.1016/S0008-6223(00)00048-810.1016/S0008-6223(00)00048-8 ↗
31. 10.1039/b800274f10.1039/b800274f ↗
32. 10.1002/adma.20040039110.1002/adma.200400391 ↗
33. 10.1039/b110487j10.1039/b110487j ↗
34. 10.1021/j100399a04510.1021/j100399a045 ↗
35. 10.1002/adma.20090281210.1002/adma.200902812 ↗
36. 10.1016/j.carbon.2010.05.02710.1016/j.carbon.2010.05.027 ↗
37. 10.1039/c1jm00013f10.1039/c1jm00013f ↗
38. 10.1021/nn102353h10.1021/nn102353h ↗
39. 10.1021/ja309164310.1021/ja3091643 ↗
40. 10.1002/smll.20100199310.1002/smll.201001993 ↗
41. 10.1002/adma.20080307810.1002/adma.200803078 ↗
42. Li X. H. · Angew Chem. Int. Ed. · 2012 · 51 · 9869
43. 10.1016/0022-1902(68)80112-510.1016/0022-1902(68)80112-5 ↗
44. 10.1038/438178a10.1038/438178a ↗
45. 10.1016/j.micromeso.2012.02.02910.1016/j.micromeso.2012.02.029 ↗
46. 10.1002/adfm.20110292010.1002/adfm.201102920 ↗
47. 10.1002/adma.20120342210.1002/adma.201203422 ↗
48. 10.1002/anie.20120672010.1002/anie.201206720 ↗
49. 10.1002/smll.20120086110.1002/smll.201200861 ↗
50. 10.1021/ar300122m10.1021/ar300122m ↗
51. 10.1126/science.120875910.1126/science.1208759 ↗
52. 10.1002/anie.20110925710.1002/anie.201109257 ↗
53. 10.1126/science.113219510.1126/science.1132195 ↗
54. 10.1021/ja402552h10.1021/ja402552h ↗
55. 10.1016/S0008-6223(00)00183-410.1016/S0008-6223(00)00183-4 ↗
56. 10.1016/j.jpowsour.2005.09.00810.1016/j.jpowsour.2005.09.008 ↗
57. 10.1016/j.jpowsour.2006.02.06510.1016/j.jpowsour.2006.02.065 ↗
58. 10.1038/nmat229710.1038/nmat2297 ↗