Review—Orbital Physics: Glorious Past, Bright Future
Source abstract
Abstract
Transition metal (TM) compounds present a very big class of materials with quite diverse properties. There are insulators, metals and systems with insulator–metal transitions among them; most magnetic systems are TM compounds; there are also (high- T c ) superconductors among them. Their very rich properties are largely determined by the strong interplay of different degrees of freedom: charge; spin; orbital; lattice. Orbital effects play a very important role in these systems—and not only in them! The study of this field, initiated by Goodenough almost 70 years ago, turned out to be very fruitful and produced a lot of important results. In this short review I discuss the basics of orbital physics and summarize the main achievements in this big field, in which Goodenough played a pivotal role, and which are nowadays widely used to explain many properties of TM compounds. In the main part of the text I discuss novel developments and perspectives in orbital physics, which is still a very active field of research, constantly producing new surprises.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Advanced Condensed Matter Physics · Magnetic and transport properties of perovskites and related materials · Iron-based superconductors research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Discussion after the talk of de Boer and Verwey
2. Khomskii · 2014
3. On the Relation between the Liquid and the Gaseous States of Metals, Acta Phys.-Chim
4. Landau · On the Relation between the Liquid and the Gaseous States of Metals ZhETF · 1944 · 14 · 32
5. The basis of the electron theory of metals, with special reference to the transition metals10.1088/0370-1298/62/7/303 ↗
6. New Approach to the Theory of Superexchange Interactions10.1103/PhysRev.115.2 ↗
7. Electron correlations in narrow energy bands
8. Jahn-Teller effect and magnetism: transition metal compounds10.1070/PU1982v025n04ABEH004537 ↗
9. Orbital Physics in Transition-Metal Oxides10.1126/science.288.5465.462 ↗
10. Role of orbitals in the physics of correlated electron systems10.1238/Physica.Regular.072a00CC8 ↗
11. Orbital Order and Fluctuations in Mott Insulators10.1143/PTPS.160.155 ↗
12. Orbital physics in transition metal compounds: new trends10.3367/UFNe.2017.08.038196 ↗
13. Orbital Effects in Solids: Basics, Recent Progress, and Opportunities10.1021/acs.chemrev.0c00579 ↗
14. Goodenough · 1963
15. Theory of the Role of Covalence in the Perovskite-Type Manganites [La, M(II)]MnO310.1103/PhysRev.100.564 ↗
16. An interpretation of the magnetic properties of the perovskite-type mixed crystals La 1−x Sr x CoO 3−λ10.1016/0022-3697(58)90107-0 ↗
17. Theory of the Magnetic Properties of Ferrous and Cobaltous Oxides10.1143/PTP.17.177 ↗
18. Superexchange interaction and symmetry properties of electron orbitals10.1016/0022-3697(59)90061-7 ↗
19. Kanamori · J. Appl. Phys. Suppl. · 1960 · 31 · 14S10.1063/1.1984590 ↗
20. Collective electron ferromagnetism10.1098/rspa.1938.0066 ↗
21. Interaction between the d-Shells in the Transition Metals. II. Ferromagnetic Compounds of Manganese with Perovskite Structure10.1103/PhysRev.82.403 ↗
22. Effects of Double Exchange in Magnetic Crystals10.1103/PhysRev.118.141 ↗
23. Electronic structure and magnetic properties of pyroxenes (Li,Na)TM(Si,Ge)2O6: novel low-dimensional magnets with 90° bonds10.1103/PhysRevB.77.064405 ↗
24. Spin-orbital interaction for face-sharing octahedra: realization of highly symmetric SU(4) model10.1103/PhysRevB.91.155125 ↗
25. Stability of polyatomic molecules in degenerate electronic states–I-Orbital degeneracy
26. Bersuker · 2006
27. Superexchange ordering of degenerate orbitals and magnetic structure of dielectrics with Jahn-Teller ions
28. Crystal structure and magnetic properties of the substances with orbital degeneracy, Sov
29. Mechanism for Orbital Ordering in KCuF310.1103/PhysRevLett.101.266405 ↗
30. Origin of Jahn-Teller Distortion and Orbital Order in LaMnO310.1103/PhysRevLett.104.086402 ↗
31. Unveiling hidden ferrimagnetism and giant magnetoelectricity in polar magnet Fe2Mo3O810.1038/srep12268 ↗
32. Diagonal Magnetoelectric Susceptibility and Effect of Fe Doping in the Polar Ferrimagnet Mn2Mo3O810.1103/PhysRevB.95.045142 ↗
33. Ordering of Fe and Zn Ions and the Magnetic Properties10.1134/S0021364019120026 ↗
34. Microscopic Toy model for Magnetoelectric Effect in Polar Fe2Mo3O810.1103/PhysRevMaterials.3.114402 ↗
35. Nonpolar-to-Polar Trimerization Transitions in the S = 1 Kagome Magnet Na2Ti3Cl810.1021/acs.inorgchem.9b01110 ↗
36. Multiferroicity and skyrmions carrying electric polarization in GaV4S810.1126/sciadv.1500916 ↗
37. Polar Dynamics at the Jahn-Teller Transition in Ferroelectric GaV4S810.1103/PhysRevLett.115.207601 ↗
38. Charge Order at the Frontier between the Molecular and Solid States in Ba3NaRu2O910.1103/PhysRevLett.108.217205 ↗
39. Spin-orbit entangled j = 1/2 moments in Ba2CeIrO6—a frustrated fcc quantum magnet10.1103/PhysRevB.100.085139 ↗
40. Hexagonal Perovskites as Quantum Materials10.1021/acs.chemrev.0c00622 ↗
41. Three-site transition-metal clusters: going from localized electrons to molecular orbitals10.1103/PhysRevB.102.174448 ↗
42. Oxides which show a metal-to-insulator transition at the Néel temperature10.1103/PhysRevLett.3.34 ↗
43. The two components of the crystallographic transition in VO210.1016/0022-4596(71)90091-0 ↗
44. Spin Singlet Formation in MgTi2O4: Evidence of a Helical Dimerization Pattern10.1103/PhysRevLett.92.056402 ↗
45. Radaelli · Formation of isomorphic Ir3. and Ir4. octamers and spin dimerization in the spinel CuIr2S4, Nature · 2002 · 416 · 155
46. Electric and magnetic properties of Li x V 2−x O210.1016/0025-5408(69)90023-3 ↗
47. Orbital ordering in two-dimensional triangular lattice10.1103/PhysRevLett.78.1323 ↗
48. Anomalous Metallic State in the Vicinity of Metal to Valence-Bond Solid Insulator Transition in LiVS210.1103/PhysRevLett.103.146405 ↗
49. New-Type Phase Transition of Li2RuO3 with Honeycomb Structure10.1143/JPSJ.76.033705 ↗
50. Classical Dimers and Dimerized Superstructure in an Orbitally Degenerate Honeycomb Antiferromagnet10.1103/PhysRevLett.100.147203 ↗
51. Spontaneous formation of vanadium “molecules” in a geometrically frustrated crystal: AlV2O410.1103/PhysRevLett.96.086406 ↗
52. Persistent three- and four-atom orbital molecules in the spinel AlV 2O410.1103/PhysRevMaterials.1.052003 ↗
53. Successive Orbital Ordering Transitions in NaVO210.1103/PhysRevLett.101.166402 ↗
54. Orbitally induced Peierls state in spinels10.1103/PhysRevLett.94.156402 ↗
55. Comment on “Spin-Lattice Coupling and the Emergence of the Trimerized Phase in the S = 1 Kagome Antiferromagnet Na2Ti3Cl810.1103/PhysRevLett.127.049701 ↗
56. Khomskii · Orbital Peierls mechanism of the formation of molecular clusters in Na2Ti3Cl8 and in similar systems, arXiv · 2021 · 2108 · 01844
57. Orbital-selective Mott-insulator transition in Ca 2−x Sr x RuO410.1140/epjb/e20020021 ↗
58. Strong Correlations from Hund's Coupling10.1146/annurev-conmatphys-020911-125045 ↗
59. Covalent bonds against magnetism in transition metal compounds10.1073/pnas.1606367113 ↗
60. Synthesis, structure and magnetic properties of the S = 1/2 one-dimensional antiferromagnet Y5Re2O1210.1016/S0022-4596(03)00033-1 ↗
61. CrO2: Self-doped double-exchange ferromagnetic oxides10.1103/PhysRevLett.80.4305 ↗
62. Unusual valence, negative charge-transfer gaps and self-doping in transition metal compounds
63. Sawatzky · in Quantum Materials: Experiment and Theory, Lecture Notes of the Jülich Autumn School · 2016 · 6
64. Orbital ordering in charge transfer insulators10.1103/PhysRevLett.92.167201 ↗
65. Spin-orbital liquid in Ba3CuSb2O9 stabilized by oxygen holes10.1103/PhysRevMaterials.5.075002 ↗
66. Compass models: Theory and physical motivations10.1103/RevModPhys.87.1 ↗
67. Anyons in an Exactly Solved Model and Beyond10.1016/j.aop.2005.10.005 ↗
68. Mott Insulators in the Strong Spin-Orbit Coupling Limit: From Heisenberg to a Quantum Compass and Kitaev Models10.1103/PhysRevLett.102.017205 ↗
69. Trebst · Kitaev materials, in Topological Matter: Topological Insulators, Skyrmions, Majoranas, Lecture Notes of the 48th IFF Spring School; Forschungszentrum Jülich: Jülich, Germany · 2017
70. Kitaev quantum spin liquid–concept and materialization10.1038/s42254-019-0038-2 ↗
71. Orbital Frustration at the Origin of the Magnetic Behavior in LiNiO210.1103/PhysRevLett.86.3638 ↗
72. Orbital ordering in frustrated Jahn-Teller systems10.1103/PhysRevLett.89.227203 ↗
73. Abragam · 1970
74. Landau · 1965
75. Spin-Orbit-Entangled Electronic Phases in 4d and 5d Transition-Metal Compounds10.7566/JPSJ.90.062001 ↗
76. Jahn-Teller effect and spin-orbit coupling: friends or foes?10.1103/PhysRevX.10.031043 ↗
77. Streltsov · 2022
78. Colloquium: Topological insulators10.1103/RevModPhys.82.3045 ↗
79. Topological insulators and superconductors10.1103/RevModPhys.83.1057 ↗
80. Topological Insulator Materials10.7566/JPSJ.82.102001 ↗
81. Dynamical Jahn-Teller Effect in Paramagnetic Resonance Spectra: Orbital Reduction Factors and Partial Quenching of Spin-Orbit Interaction10.1103/PhysRev.138.A1727 ↗
82. Effect of Linear Jahn-Teller Coupling on Paramagnetic Resonance in a 2E State10.1103/PhysRev.166.307 ↗
83. Orbital Liquid in Three-Dimensional Mott Insulator: LaTiO310.1103/PhysRevLett.85.3950 ↗
84. Order from disorder: Quantum spin gap in magnon spectra of LaTiO310.1103/PhysRevB.64.212405 ↗
85. Magnetic Neutron Scattering Study of YVO3: Evidence for an Orbital Peierls State10.1103/PhysRevLett.91.257202 ↗
86. Quantum Versus Jahn-Teller Orbital Physics in YVO3 and LaVO310.1103/PhysRevLett.93.176404 ↗
87. Jahn-Teller versus quantum effects in the spin-orbital material LaVO310.1103/PhysRevB.91.161104 ↗
88. Crystal structure and magnetic properties of the substances with orbital degeneracy, Sov
89. Role of Local Geometry in the Spin and Orbital Structure of Transition Metal Compounds10.1134/S1063776116030079 ↗
90. Emergent SU(4) Symmetry in α-ZrCl3 and Crystalline Spin-Orbital Liquids10.1103/PhysRevLett.121.097201 ↗
91. Can the highly symmetric SU(4) spin-orbital model be realized in α-ZrCl3?10.1134/S002136402022004X ↗
92. Spin-orbital frustrations and anomalous metallic state in iron-pnictide superconductors10.1103/PhysRevB.79.054504 ↗
93. Preemptive nematic order, pseudogap, and orbital order in the iron pnictides10.1103/PhysRevB.85.024534 ↗
94. Orbital-Selective Mott Phase in Multiorbital Models for Alkaline Iron Selenides K1−x Fe 2−y Se210.1103/PhysRevLett.110.146402 ↗
95. Coherence-incoherence crossover in the normal state of iron oxypnictides and importance of Hund's rule coupling10.1088/1367-2630/11/2/025021 ↗
96. Spin-orbital superexchange physics emerging from interacting oxygen molecules in KO210.1088/1367-2630/10/1/013035 ↗
97. Spin-orbital physics for p-orbitals in alkali RO 2 hyperoxides—generalization of the Goodenough-Kanamori rules10.1209/0295-5075/96/27001 ↗
98. Unexpected 3 + valence or iron in FeO2, a geologically important material lying “in between” oxides and peroxides10.1038/s41598-017-13312-4 ↗
99. Collective modes and skyrmion excitations in graphene SU(4) quantum Hall ferromagnets10.1103/PhysRevB.74.075423 ↗
100. Oxide spin-orbitronics: New routes towards low-power electrical control of magnetization in oxide heterostructures10.7567/JJAP.57.0902A4 ↗