Scavenging Materials to Stabilize LiPF₆‐Containing Carbonate‐Based Electrolytes for Li‐Ion Batteries

Abstract In conjunction with electrolyte additives used for tuning the interfacial structures of electrodes, functional materials that eliminate or deactivate reactive substances generated by the degradation of LiPF₆‐containing electrolytes in lithium‐ion batteries offer a wide range of electrolyte formulation opportunities. Herein, the recent advancements in the development of: (i) scavengers with high selectivity and affinity toward unwanted species and (ii) promoters of ion‐paired LiPF₆ dissociation are highlighted, showing that the utilization of the above additives can effectively mitigate the problem of electrolyte instability that commonly results in battery performance degradation and lifetime shortening. A deep mechanistic understanding of LiPF₆‐containing electrolyte failure and the action of currently developed additives is demonstrated to enable the rational design of effective scavenging materials and thus allow the fabrication of highly reliable batteries.