Tin‐doped bismuth dendrites for highly efficient electrocatalytic reduction of CO₂ by using bipolar membrane in ultrathin liquid reactor

Abstract Electrochemical CO₂ reduction reaction is a promising protocol to achieve a carbon‐neutral cycle. Herein, we report a general strategy to regulate the growth of Sn‐doped Bi dendritic electrode with numerous labyrinthine and porous channels to provide abundant tips, edges, terraces, and low coordination sites for efficient conversion of CO₂ into formate. As a result, the dendritic Sn‐doped Bi achieves a high partial current density (30 mA/cm²), a high Faradic efficiency of formate (95.5%), and a long‐term durability (>60 h). Most remarkably, the self‐made bipolar membrane can effectually prohibit the cross‐over of formate from cathode to anode and the oxidization of small organic molecules in anode can promote the production of formate on both anode and cathode sides. This work provides helpful insights to the design of electrocatalysts, bipolar membrane, and ultrathin liquid reactor. image