journal article·2021-10Open access

Recent advance in structure regulation of high‐capacity Ni‐rich layered oxide cathodes

Lang Qiu, Mengke Zhang, Yang Song, Yao Xiao, Zhenguo Wu, Wei Xiang, Yuxia Liu, Gongke Wang, Yan Sun, Jun Zhang, Bin Zhang, Xiaodong Guo

EcoMat· Volume 3· Issue 5

Abstract

Abstract High‐capacity layered oxide Ni‐rich cathodes are attractive to enhance the driving‐range of electric vehicles because of its preferential costs. Nevertheless, in Ni‐rich cathodes, there are still many issues such as microcracks generation along grain boundaries and interface side reaction between active substance and electrolyte, resulting in the rapidly deterioration of electrochemical property. Herein, improving the performance of Ni‐based cathodes by structural regulation is summarized. The remaining challenges and outlook are discussed as well. image
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Chemical Engineering Sichuan University Chengdu Sichuan China

Institute of Microscale Optoelectronics, College of Physics and Optoelectronic Engineering Shenzhen University Shenzhen Guangdong China

College of Materials and Chemistry & Chemical Engineering Chengdu University of Technology Chengdu Sichuan China

The Key Laboratory of Life‐Organic Analysis, Key Laboratory of Pharmaceutical, Intermediates and Analysis of Natural Medicine, School of Chemistry and Chemical Engineering Qufu Normal University Qufu Shandong China

School of Materials Science and Engineering Henan Normal University Xinxiang Henan China

School of Mechanical Engineering Chengdu University Chengdu Sichuan China

Ruyuan Dongyang Guangcixing Material Limited Company Shaoguan Guangdong China

Yibin Libao New Material Co., Ltd Yibin Sichuan China

Funding

China Postdoctoral Science Foundation · National Postdoctoral Program for Innovative Talents · Department of Science and Technology of Sichuan Province · State Key Laboratory of Polymer Materials Engineering · Chinese National Science Foundation

References (100+)

Show source-provided references
1. Polyanion and cation co‐doping stabilized Ni‐rich Ni‐co‐Al material as cathode with enhanced electrochemical performance for Li‐ion battery
2. Evolution and expansion of Li concentration gradient during charge‐discharge cycling10.1038/s41467-021-24120-w ↗
3. Large‐scale synthesis of the stable co‐free layered oxide cathode by the synergetic contribution of multielement chemical substitution for practical sodium‐ion battery10.34133/2020/1469301 ↗
4. 10.1016/j.egypro.2019.01.78310.1016/j.egypro.2019.01.783 ↗
5. 10.1039/C8MH00133B10.1039/C8MH00133B ↗
6. 10.1149/2.0251701jes10.1149/2.0251701jes ↗
7. 10.1002/anie.20170377210.1002/anie.201703772 ↗
8. 10.1039/D0CS00021C10.1039/D0CS00021C ↗
9. 10.1016/j.xcrp.2021.10054710.1016/j.xcrp.2021.100547 ↗
10. 10.1021/ar200224h10.1021/ar200224h ↗
11. 10.1039/C9TA06579B10.1039/C9TA06579B ↗
12. 10.1038/s41467-019-11299-210.1038/s41467-019-11299-2 ↗
13. Cation ordering and redox chemistry of layered Ni‐rich Li x Ni1‐2y Co y Mn y O2: An operando Raman spectroscopy study10.1021/acs.chemmater.9b03202 ↗
14. 10.1002/anie.20200814410.1002/anie.202008144 ↗
15. Cobalt‐free high‐capacity Ni‐rich layered Li[Ni0.9Mn0.1]O2 cathode10.1002/aenm.201903179 ↗
16. 10.1021/acsenergylett.8b0249910.1021/acsenergylett.8b02499 ↗
17. 10.1021/acsami.8b1037210.1021/acsami.8b10372 ↗
18. Synthesis and characterization of LiAl1/4Ni3/4O2 (R3m) for lithium‐ion (shuttlecock)batteries10.1149/1.2048458 ↗
19. 10.1016/S0378-7753(99)00221-910.1016/S0378-7753(99)00221-9 ↗
20. 10.1016/S0378-7753(00)00407-910.1016/S0378-7753(00)00407-9 ↗
21. 10.1016/j.elecom.2007.07.03310.1016/j.elecom.2007.07.033 ↗
22. 10.1246/cl.2001.64210.1246/cl.2001.642 ↗
23. Layered Li[Ni x Co1‐2x Mn x ]O2 cathode materials for lithium‐ion batteries10.1149/1.1413182 ↗
24. Structural and electrochemical properties of layered Li[Ni0.5Mn0.5]1‐x Co x O2 positive materials synthesized by ultrasonic spray pyrolysis method
25. Structure and electrochemistry of Li[Ni x Co1‐2x Mn x ]O2 (0≤x≤1/2)
26. 10.1016/j.nanoen.2018.04.06210.1016/j.nanoen.2018.04.062 ↗
27. 10.1002/aenm.20170202810.1002/aenm.201702028 ↗
28. 10.1002/anie.20140926210.1002/anie.201409262 ↗
29. 10.1149/1.195268710.1149/1.1952687 ↗
30. 10.1016/j.jpowsour.2005.11.08310.1016/j.jpowsour.2005.11.083 ↗
31. Structural and electrochemical properties of layered Li[Ni1‐2x Co x Mn x ]O2 (x =0.1–0.3) positive electrode materials for Li‐ion batteries10.1149/1.2769831 ↗
32. Synthesis and characterization of LiNi0.6Mn0.4‐x Co x O2 as cathode materials for Li‐ion batteries10.1016/j.jpowsour.2008.12.046 ↗
33. 10.1016/j.jpowsour.2013.01.06310.1016/j.jpowsour.2013.01.063 ↗
34. 10.1002/aenm.20130158310.1002/aenm.201301583 ↗
35. 10.1016/j.jpowsour.2016.07.03910.1016/j.jpowsour.2016.07.039 ↗
36. 10.1021/acsami.6b0451610.1021/acsami.6b04516 ↗
37. 10.1039/C6TA09921A10.1039/C6TA09921A ↗
38. 10.1039/C7TA11346C10.1039/C7TA11346C ↗
39. 10.1016/S0378-7753(03)00194-010.1016/S0378-7753(03)00194-0 ↗
40. 10.1039/b811802g10.1039/b811802g ↗
41. 10.1016/j.nanoen.2020.10502110.1016/j.nanoen.2020.105021 ↗
42. 10.1016/j.electacta.2015.08.12210.1016/j.electacta.2015.08.122 ↗
43. 10.1002/aenm.20170178810.1002/aenm.201701788 ↗
44. Thermodynamic description of the LiNiO2‐NiO2 pseudo‐binary system and extrapolation to the Li(co,Ni)O2‐(co,Ni)O2 system10.1016/j.calphad.2012.02.006 ↗
45. 10.1557/mrs2002.19610.1557/mrs2002.196 ↗
46. Characterization and cathode performance of Li1‐x Ni1+x O2 prepared with the excess lithium method10.1016/0167-2738(95)00144-U ↗
47. 10.1016/j.ensm.2016.10.00710.1016/j.ensm.2016.10.007 ↗
48. 10.1021/cm201452q10.1021/cm201452q ↗
49. 10.1002/adfm.20120069310.1002/adfm.201200693 ↗
50. A short review on surface chemical aspects of Li batteries: A key for a good performance10.1016/j.jpowsour.2008.09.084 ↗
51. 10.1016/j.jpowsour.2005.03.09110.1016/j.jpowsour.2005.03.091 ↗
52. Prevention of the micro cracks generation in LiNiCoAlO2 cathode by the restriction of ΔDOD
53. 10.1038/s41467-021-24893-010.1038/s41467-021-24893-0 ↗
54. Dual‐anion ionic liquid electrolyte enables stable Ni‐rich cathodes in lithium‐metal batteries
55. 10.1021/acs.jpcc.6b1288510.1021/acs.jpcc.6b12885 ↗
56. In‐situ X‐ray‐diffraction and electrochemical studies of Li1‐x NiO210.1016/0167-2738(93)90317-V ↗
57. 10.1002/aenm.20200052110.1002/aenm.202000521 ↗
58. 10.1021/acsenergylett.9b0230210.1021/acsenergylett.9b02302 ↗
59. 10.1021/acs.chemmater.7b0526910.1021/acs.chemmater.7b05269 ↗
60. 10.1021/acsenergylett.7b0030410.1021/acsenergylett.7b00304 ↗
61. Prevention of the micro cracks generation in LiNiCoAlO2 cathode by the restriction of delta DOD10.1149/1.4717964 ↗
62. 10.1016/j.jpowsour.2014.02.10310.1016/j.jpowsour.2014.02.103 ↗
63. 10.1016/j.jpowsour.2014.02.01810.1016/j.jpowsour.2014.02.018 ↗
64. 10.1021/acsenergylett.9b0073310.1021/acsenergylett.9b00733 ↗
65. 10.1038/nmat241810.1038/nmat2418 ↗
66. 10.1002/adfm.20090173010.1002/adfm.200901730 ↗
67. 10.1021/acs.chemmater.7b0142510.1021/acs.chemmater.7b01425 ↗
68. 10.1021/acsaem.9b0111610.1021/acsaem.9b01116 ↗
69. Microstructure‐controlled Ni‐rich cathode material by microscale compositional partition for next‐generation electric vehicles
70. 10.1038/nmat343510.1038/nmat3435 ↗
71. 10.1002/adfm.20120069910.1002/adfm.201200699 ↗
72. 10.1021/jp409788710.1021/jp4097887 ↗
73. Compositionally graded cathode material with long‐term cycling stability for electric vehicles application
74. 10.1039/C9TA00224C10.1039/C9TA00224C ↗
75. Shape‐controlled synthesis of hierarchically layered lithium transition‐metal oxide cathode materials by shear exfoliation in continuous stirred‐tank reactors
76. 10.1002/adma.20100157810.1002/adma.201001578 ↗
77. 10.1002/adfm.20120053610.1002/adfm.201200536 ↗
78. 10.1039/c3ta01618h10.1039/c3ta01618h ↗
79. 10.1002/aenm.20180396310.1002/aenm.201803963 ↗
80. 10.1021/acsenergylett.6b0015010.1021/acsenergylett.6b00150 ↗
81. 10.1002/adfm.20150143010.1002/adfm.201501430 ↗
82. 10.1021/nl502285910.1021/nl5022859 ↗
83. 10.1039/C5TA05657H10.1039/C5TA05657H ↗
84. 10.1039/C6EE01134A10.1039/C6EE01134A ↗
85. 10.1002/adma.20140254110.1002/adma.201402541 ↗
86. 10.1007/s11581-016-1710-510.1007/s11581-016-1710-5 ↗
87. Factors that affect Li mobility in layered lithium transition metal oxides10.1103/PhysRevB.74.094105 ↗
88. 10.1016/S0013-4686(02)00317-110.1016/S0013-4686(02)00317-1 ↗
89. 10.1149/1.305610910.1149/1.3056109 ↗
90. 10.1149/2.005207jes10.1149/2.005207jes ↗
91. Application of first‐principles calculations to the design of rechargeable Li‐batteries10.1016/S0927-0256(97)00029-3 ↗
92. 10.1038/s41560-020-00693-610.1038/s41560-020-00693-6 ↗
93. 10.1039/D0TA00260G10.1039/D0TA00260G ↗
94. 10.1016/S0378-7753(01)00900-410.1016/S0378-7753(01)00900-4 ↗
95. 10.1016/j.electacta.2018.08.12410.1016/j.electacta.2018.08.124 ↗
96. 10.1039/D0TA06375D10.1039/D0TA06375D ↗
97. 10.1039/C8SC03385D10.1039/C8SC03385D ↗
98. 10.1039/C9TA02803J10.1039/C9TA02803J ↗
99. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium‐ion batteries
100. 10.1002/adfm.20180882510.1002/adfm.201808825 ↗