journal article·2019-07-12

Expanding Interlayer Spacing in MoS2 for Realizing an Advanced Supercapacitor

Debasish Sarkar, Debanjan Das, Shyamashis Das, Ankit Kumar, Satish Patil, Karuna Kar Nanda, D. D. Sarma, Ashok Shukla

ACS Energy Letters· Volume 4· Issue 7
Publisher page

Abstract

Charge-storage mechanism of free-standing MoS2/r-GO (r-GO = reduced graphene oxide) hybrid nanoflakes on molybdenum (Mo) foil in Na2SO4 solution is elucidated for realizing a high-performance asymmetric supercapacitor (ASC). Thiourea that acts primarily as sulfur source also helps intercalating ammonium ions, which along with r-GO facilitate in situ exfoliation of MoS2, producing hierarchical MoS2 with expanded interlayer spacing. This interlayer expansion in MoS2 facilitates Na+-ions intercalation/deintercalation and ensures enhanced capacitance, rate capability, and cycling stability of the capacitor. Besides exhibiting attractive energy-cum-power traits, the 2 V MoS2/r-GO//Fe2O3/MnO2 ASC shows compelling cycling performance for over 20 000 cycles in an aqueous electrolyte.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · MXene and MAX Phase Materials · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Physics, Malaviya National Institute of Technology Jaipur, Rajasthan 302017, India

Funding

Engineering and Physical Sciences Research Council · Department of Science and Technology, Ministry of Science and Technology

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