journal article·2015-04

Linear thiophene-containing π-conjugated aldehydes with aggregation-induced emission for building solid red luminophors

Kunpeng Guo, Zhixiang Gao, Jun Cheng, Yang Shao, Xiaoqing Lu, Hua Wang

Dyes and Pigments· Volume 115
Publisher page

Abstract

Abstract Two linear thiophene-containing π-conjugated aldehydes 4-(thiophen-2-yl)benzaldehyde and 2,5-bis[4-(formyl)phenyl]thiophene exhibiting aggregation-induced emission (AIE) were demonstrated. The photophysical properties of the two aldehydes in solution and THF/H 2 O mixtures were studied, and aggregates formed with different water fractions were studied by scanning electron microscopy. Results indicated that amorphous nanoscale aggregates exhibit distinct AIE behavior when assembled in solutions with appropriate water contents. Condensation of 1,3-indandione with 4-(thiophen-2-yl)benzaldehyde generated a new luminophor 2-[4-(thiophen-2-yl)benzylidene]-2H-indene-1,3-dione; this product presents as a solid powder that emits intensely red photoluminescence at 620 nm with a quantum yield of 12.8%.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence and Fluorescent Materials · Molecular Sensors and Ion Detection · Polydiacetylene-based materials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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