Emergence of Local Magnetic Moment in Ternary TaWSe ₂ Single Crystal via Atomic Clustering

Abstract Ternary transition metal dichalcogenides (TMDs) provide a versatile platform to explore novel electronic and magnetic ground states via compositional substitution and local structural modulations. Using a combination of scanning tunneling microscopy and spectroscopy (STM/S), magnetic property measurements, and density functional theory (DFT) calculations, the emergence of local magnetic moments driven by the clustering of Ta atoms in ternary TaWSe ₂ single crystals is analyzed. STM topography reveals triangular clusters of Ta atoms embedded within W‐rich regions of TaWSe ₂ . These clusters exhibit a consistent shape and an orderly arrangement throughout the surfaces. DFT calculations show that these Ta clusters induce local strain, giving rise to localized magnetic moments. The magnetic behavior is further corroborated by temperature‐dependent magnetization measurements, which exhibit a magnetic anomaly at ∼50 K. This study offers a pathway to engineer magnetism in TMD systems with potential applications in spintronic and quantum materials.