journal article·2023-07Open access

Secondary‐Phase‐Induced Charge–Discharge Performance Enhancement of Co‐Free High Entropy Spinel Oxide Electrodes for Li‐Ion Batteries (Adv. Funct. Mater. 30/2023)

Thi Xuyen Nguyen, Jagabandhu Patra, Chia‐Chien Tsai, Wen‐Ye Xuan, Hsin‐Yi Tiffany Chen, Matthew S. Dyer, Oliver Clemens, Ju Li, Subhasish Basu Majumder, Jeng‐Kuei Chang, Jyh‐Ming Ting

Advanced Functional Materials· Volume 33· Issue 30

Abstract

Co-Free Electrodes In article number 2300509, Jyh-Ming Ting, Jeng-Kuei Chang, and co-workers prepare, a Co-free cubic high entropy spinel oxide and cubic+tetragonal high entropy spinel oxide (HESO (C+T)) using solvothermal and hydrothermal methods, respectively. The secondary tetragonal spinel phase in HESO (C+T) introduces phase boundaries and extra defects/oxygen vacancies, enhancing the redox kinetics and electroactivity during lithiation/delithiation. HESO (C+T)||LiNi0.8Co0.1Mn0.1O2 cell shows an attractive gravimetric energy density of ∼610 Wh kg−1.
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Research context

OpenAlex topics: Semiconductor materials and devices · Transition Metal Oxide Nanomaterials · Advancements in Battery Materials

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Affiliations

Department of Materials Science and Engineering National Cheng Kung University 1 University Road Tainan 70101 Taiwan

Hierarchical Green‐Energy Materials (Hi‐GEM) Research Center National Cheng Kung University 1 University Road Tainan 70101 Taiwan

Department of Materials Science and Engineering National Yang Ming Chiao Tung University 1001 University Road Hsinchu 30010 Taiwan

Department of Engineering and Systems Science National Tsing Hua University Hsinchu 300044 Taiwan

School of Chemistry University of Liverpool Crown St Liverpool L69 7ZD UK

Materials Innovation Factory University of Liverpool 51 Oxford St Liverpool L7 3NY UK

Institut für Materialwissenschaft, Chemische Materialsynthese Universität Stuttgart Heisenbergstraße 3 70569 Stuttgart Germany

Department of Nuclear Science and Engineering and Department of Materials Science and Engineering Massachusetts Institute of Technology 77 Massachusetts Avenue Cambridge MA 02139 USA

Materials Science Centre Indian Institute of Technology Kharagpur West Bengal 721302 India

Department of Industrial and Manufacturing Systems Engineering Kansas State University Manhattan KS 66506 USA

Department of Chemical Engineering Chung Yuan Christian University 200 Chung Pei Road Taoyuan 32023 Taiwan

References

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