DataVXDigest Journal of Nanomaterials and BiostructuresPaper
journal article·2025-01-15Open access

Simultaneously reinforce and de-color nanocellulose/lignin composite films by tuning hydroxyl groups with sodium borohydride

School of Environmental and Natural Resources, Zhejiang University of Science and Technology, Hangzhou 310023, China, X. G. Liu, S. Y. Zeng, Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China, Q. F. Wang, Hangzhou Weipack Technology Co., Ltd, Hangzhou 310018, China, J. Li, School of Environmental and Natural Resources, Zhejiang University of Science and Technology, Hangzhou 310023, China, X. Tong, School of Environmental and Natural Resources, Zhejiang University of Science and Technology, Hangzhou 310023, China, J. B. Chen, ChenWinbon Schoeller New Materials Co., Ltd., Quzhou 324400, China, D. L. Guo, School of Environmental and Natural Resources, Zhejiang University of Science and Technology, Hangzhou 310023, China, H. F. Zhao, School of Environmental and Natural Resources, Zhejiang University of Science and Technology, Hangzhou 310023, China, X. H. Chen, School of Environmental and Natural Resources, Zhejiang University of Science and Technology, Hangzhou 310023, China

Digest Journal of Nanomaterials and Biostructures· Volume 20· Issue 1
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Source abstract

Abstract

Researchers utilized NaBH4 to gently modify alkali lignin, resulting in L-Sx-ty-Pz with high hydroxyl value and decolorization, significantly enhancing the strength of composite films with cellulose nanofibers (CNF). Without strict pH control, the hydroxyl content of the modified lignin reached as high as 9.14 mmol/g. The CF/L-S1-t120-Pu composite film achieved a maximum stress of 45.33 MPa, representing a 116% and 77% increase compared to pure CNF and crude alkali lignin composite films, respectively. The reduction effect of NaBH4 imparted transparency to the film, broadening its applications. Additionally, the film's excellent antibacterial and flame-retardant properties provide strong support for industrial utilization.
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Research context

NanomaterialsComposites

OpenAlex topics: Advanced Cellulose Research Studies · Lignin and Wood Chemistry · Dyeing and Modifying Textile Fibers

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. [1] Q. Q. Xia, C. J. Chen, Y. G. Yao, G. J. Li, S. M. He, Y. B. Zhou, T. Li, X. J. Pan, Y. Yao, L. B. Hu, Nat. Sustain. 4, 627-635 (2021); https://doi.org/10.1038/s41893-021-00702-w10.1038/s41893-021-00702-w ↗
2. [2] A. G. Morena, T. Tzanov, Royal Society of Chemistry publishes. 4, 4447-4469 (2022); https://doi.org/10.1039/D2NA00423B10.1039/D2NA00423B ↗
3. [3]. X. Q. Li, J. Y. Li, X. Y. Shen, M. Y. Cao, Y. Wang, W. S. Zhang, Y. L. Xu, Z. Ling, S. Chen, F. Xu, ACS Sustainable Chemistry & Engineering. 12, 5427-5435 (2024); https://doi.org/10.1021/acssuschemeng.3c0707610.1021/acssuschemeng.3c07076 ↗
4. [4] H. T. Yang, B. Yu, X. D. Xu, S. Bourbigot, H. Wang, P. G. Song, Green Chem. 22, 2129-2161 (2020); https://doi.org/10.1039/D0GC00449A10.1039/D0GC00449A ↗
5. [5] R. Tian, C. Wang, W. K. Jiang, S. Janaswamy, G. H. Yang, X. X. Ji, Small. 22, 2309651 (2024).
6. [6] Y. Deng, Q. Q. Guan, L. He, L. C . Peng, J. H. Zhang, Carbohydr. Polym. 263, 117981 (2021); https://doi.org/10.1016/j.carbpol.2021.11798110.1016/j.carbpol.2021.117981 ↗
7. [7] S. H. Wang, Hao, Y. L. He, Q. X. He, Q. Q. Gao, Thermoplast. Compos. Mater. 08927057241233566 (2024).
8. [8] T. Luo, C. Wang, X. X. Ji, G. H. Yang, J. C. Chen, C. G. Yoo, S. Janaswamy, G. J. Lyu, International Journal of Biological Macromolecules. 183, 781-789 (2021); https://doi.org/10.1016/j.ijbiomac.2021.05.00510.1016/j.ijbiomac.2021.05.005 ↗
9. [9] J. F. Ou, S. N. Hu, L. Yao, Y. Chen, H. S. Qi, F. X. Yue, Chemical Engineering Journal. 453, 139770 (2023); https://doi.org/10.1016/j.cej.2022.13977010.1016/j.cej.2022.139770 ↗
10. [10] X. Z. Wang, Q. Q. Xia, S. S. Jing, C, Li, Q. Y. Chen, B. Chen, Z. Q. Pang, B. Jiang, W. T. Gan, G. Chen, M. J. Cui, L. B. Hu, T. Li, Small. 17, 2008011 (2021); https://doi.org/10.1002/smll.20200801110.1002/smll.202008011 ↗
11. [11] B. Jiang, C.J. Chen, Z.Q. Liang, S. M. He, Y. D. Kuang, J. W. Song, R. Y. Mi, G. G. Chen, M. L. Jiao, L. B. Hu. Advanced Functional Materials. 30, 1906307 (2020); https://doi.org/10.1002/adfm.20190630710.1002/adfm.201906307 ↗
12. [12] M. Farooq, T. Zou, G. Riviere, M. H. Österberg Sipponen, M. Strong, Biomacromolecules 20, 693-704 (2019); https://doi.org/10.1021/acs.biomac.8b0136410.1021/acs.biomac.8b01364 ↗
13. [13] J. L. Wang, W. Chen, T. T. Dong, H. Q. Wang, S. R Si, X. S. Li Green Chem. 23, 10062- 10070 (2021); https://doi.org/10.1039/D1GC03906G 3610.1039/D1GC03906G ↗
14. [14] Z. Yuan, H. Liu, W. F. Yong, Q. She, J. Esteban, Green Chem. 24, 1895-1929 (2022); https://doi.org/10.1039/D1GC03851F10.1039/D1GC03851F ↗
15. [15] Q. Q. Guan, J. J. Chen, D. Chen, X. S. Chai, L. He, L. C Peng, J. H. Zhang, J. Li, Journal of Catalysis. 370, 304-309 (2019); https://doi.org/10.1016/j.jcat.2019.01.00310.1016/j.jcat.2019.01.003 ↗
16. [16] Y. Zhao, A. Tagami, G. Dobele, M. E. Lindström, O. Sevastyanova, Polymers 11, 538 (2019); https://doi.org/10.3390/polym1103053810.3390/polym11030538 ↗
17. [17] H. Y. Bian, Y. Gao, R. B. Wang, Z. L. Liu, W. B. Wu, H. Q. Dai, Cellulose. 25, 1309-1318 (2018); https://doi.org/10.1007/s10570-018-1658-x10.1007/s10570-018-1658-x ↗
18. [18] S. Y. Zeng, X. g. Liu, J. Li, H. f. Zhao, D. l. Guo, X. Tong, International Journal of Biological Macromolecules. 264, 130474 (2024); https://doi.org/10.1016/j.ijbiomac.2024.13047410.1016/j.ijbiomac.2024.130474 ↗
19. [19] J. Li, H. C. Hu, X. S. Chai, AIChE Letter: Reaction Engineering, Kinetics and Catalysis. 63, 1489-1493 (2017); https://doi.org/10.1002/aic.1568110.1002/aic.15681 ↗
20. [20] S. Kirar, D. Mohne, M. Singh, V. Sagar, A. Bhise, S. Goswami, J. Bhaumik, Sustainable Materials and Technologies. 40, e00864 (2024); https://doi.org/10.1016/j.susmat.2024.e0086410.1016/j.susmat.2024.e00864 ↗
21. [21] X.Q. Li, J. Y. Li, X. Y. Shen, M. Y. Cao, Y. Wang, W. S. Zhang, Y. L. Xu, L.S. Chen, F. Xu, X. Li, ACS Sustainable Chemistry & Engineering. 12, 5427-5435 (2024); https://doi.org/10.1021/acssuschemeng.3c0707610.1021/acssuschemeng.3c07076 ↗
22. [22] A. K. Das, K. Mitra, A. J. Conte, A. Sarker, A. Chowdhury, A. J. Ragauskas, A. K. Das, International Journal of Biological Macromolecules. 261, 129753 (2024); https://doi.org/10.1016/j.ijbiomac.2024.12975310.1016/j.ijbiomac.2024.129753 ↗
23. [23] K. Sawamura, Y. Tobimatsu, H. Kamitakahara, T. Takano, ACS Sustainable Chemistry & Engineering. 5, 5424-5431 (2017); https://doi.org/10.1021/acssuschemeng.7b0074810.1021/acssuschemeng.7b00748 ↗
24. [24] T. Liu, Y. Wang, J. Zhou, M. Li, J. Yue, Polymers 13, 1349 (2021); https://doi.org/10.3390/polym1309134910.3390/polym13091349 ↗
25. [25] Y. Hua, T. Chen, Y. Tang, Industrial Crops and Products. 179, 114686 (2022); https://doi.org/10.1016/j.indcrop.2022.11468610.1016/j.indcrop.2022.114686 ↗
26. [26] Y. X. Liu, ACS Sustainable Chemistry & Engineering. 6, 5524-5532 (2018); https://doi.org/10.1021/acssuschemeng.8b0040210.1021/acssuschemeng.8b00402 ↗
27. [27] X. Wang, Y. Tang, X. Zhu, Y. Zhou, X. Hong, International Journal of Biological Macromolecules. 146, 1069-1075 (2020); https://doi.org/10.1016/j.ijbiomac.2019.09.23310.1016/j.ijbiomac.2019.09.233 ↗
28. [28] K. Jin, Y. Tang, X. Zhu, Y. Zhou, International Journal of Biological Macromolecules. 162, 1109-1117 (2020); https://doi.org/10.1016/j.ijbiomac.2020.06.20110.1016/j.ijbiomac.2020.06.201 ↗
29. [29] Figueiredo, P. P. Figueiredo, M. H. Lahtinen, M. B. Agustin, D.M. Carvalho, S.P. Hirvonen, P. A. Penttilä, ChemSusChem 14, 4718-4730 (2021); https://doi.org/10.1002/cssc.20210135610.1002/cssc.202101356 ↗
30. [30] H. Bian, H. Y. Bian, L. D. Chen, M. L. Dong, L. Y. Wang, R. B. Wang, X. L. Zhou, C. Wu, X. Wang, X. X. Ji, H. Q. Dai, International Journal of Biological Macromolecules. 166, 1578- 1585 (2021); https://doi.org/10.1016/j.ijbiomac.2020.11.03710.1016/j.ijbiomac.2020.11.037 ↗
31. [31] S. S. Nair, N. Yan, Cellulose 22, 3137-3150 (2015); https://doi.org/10.1007/s10570-015-0737-510.1007/s10570-015-0737-5 ↗
32. [32] C. Li, J. H. Shi, Y. Y. Sun, L, J. Zhang, S. Zhang, S. Wang, X. Hu, Journal of Analytical and Applied Pyrolysis. 155, 105031 (2021); https://doi.org/10.1016/j.jaap.2021.10503110.1016/j.jaap.2021.105031 ↗
33. [33] Y. He, H. C. Ye, T. T. You, F. Xu, Food Hydrocoll. 137, 108355 (2023); https://doi.org/10.1016/j.foodhyd.2022.10835510.1016/j.foodhyd.2022.108355 ↗
34. [34]. D. X. Liang, X. J. Zhu, P. Dai, X. Y. Lu, H. Q. Guo, H. Que, D. D. Wang, T. He, C. Z. Xu, H. M. Robin, Z. Y. Luo, X. L. Gu , Materials Chemistry and Physics. 259, 124101 (2021); https://doi.org/10.1016/j.matchemphys.2020.12410110.1016/j.matchemphys.2020.124101 ↗