DataVXDigest Journal of Nanomaterials and BiostructuresPaper
journal article·2023-02-20Open access

Synthesis of lanthanum metal organic framework using 1,4 benzenedicarboxylic acid

Applied Chemistry and Nano Science Laboratory, Department of Biotechnology and Chemistry, Vaal University of Technology P.O. Box X021, Vanderbjlpark 1900, South Africa, P. M. Thabede, N. D. Shooto, Applied Chemistry and Nano Science Laboratory, Department of Biotechnology and Chemistry, Vaal University of Technology P.O. Box X021, Vanderbjlpark 1900, South Africa, S. J. Modise, Applied Chemistry and Nano Science Laboratory, Department of Biotechnology and Chemistry, Vaal University of Technology P.O. Box X021, Vanderbjlpark 1900, South Africa

Digest Journal of Nanomaterials and Biostructures· Volume 18· Issue 1
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Abstract

Lanthanum nitrate and 1,4 benzenedicarboxylic acid were used to synthesize lanthanum metal organic framework (LaMOF) by conventional heating (reflux) method in dimethylformamide (DMF). The product lanthanum benzenedicarboxylic (LaBDC-MOF) structural morphology and optical properties were determined with SEM (scanning electron microscope), XRD (X-ray diffraction), TGA (thermogravimetric analysis), FTIR (Fourier-transform infrared) spectroscopy and photoluminescence spectroscopy. The characterization findings and results of LaBDC-MOF indicated that LaBDC-MOF was crystalline and significantly thermal stable. FTIR displayed that there was deprotonation in the carboxylic acidic COOH- . SEM images showed that LaBDC-MOF was composed of different sizes of rods and small needles that are polyhedral-like in shape. Luminescence properties suggested that LaBDC-MOF can be used as a fluorescent probe.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Lanthanide and Transition Metal Complexes · X-ray Diffraction in Crystallography

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