journal article·2022-03

Tuning the Interaction between Ruthenium Single Atoms and the Second Coordination Sphere for Efficient Nitrogen Photofixation (Adv. Funct. Mater. 12/2022)

Yida Zhang, Qingyu Wang, Shaokang Yang, Hengwei Wang, Dewei Rao, Tao Chen, Gongming Wang, Junling Lu, Junfa Zhu, Shiqiang Wei, Xusheng Zheng, Jie Zeng

Advanced Functional Materials· Volume 32· Issue 12
Publisher page

Abstract

Nitrogen Photofixation In article number 2112452, Xusheng Zheng and co-workers present N2 photofixation to ammonia over a CoO-supported Ru single-atom catalyst. The Ru-Co coordination between Ru single atoms (yellow spheres) and Co atoms (blue spheres) serves as an additional electron transfer channel. This channel promotes more photogenerated electrons to accumulate at Ru atoms, thus increasing photoelectron density and N2 photofixation performance over Ru active sites.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Ammonia Synthesis and Nitrogen Reduction · Advanced Nanomaterials in Catalysis

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Affiliations

National Synchrotron Radiation Laboratory University of Science and Technology of China Hefei Anhui 230029 China

Department of Applied Chemistry Hefei National Laboratory for Physical Sciences at the Microscale University of Science and Technology of China Hefei Anhui 230026 China

School of Materials Science and Engineering Jiangsu University Zhenjiang Jiangsu 212013 China

Hefei National Laboratory for Physical Sciences at the Microscale CAS Key Laboratory of Strongly‐Coupled Quantum Matter Physics Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes Department of Chemical Physics University of Science and Technology of China Hefei Anhui 230026 China

References

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