journal article·2023-12-04Open access

Characterizations of sprayed TiO2 and Cu doped TiO2 thin films prepared by spray pyrolysis method

Department of Physics, College of Education, Mustansiriyah University, Baghdad, Iraq, F. H. Jasim, H. R. Shakir, Department of Optometry, Technical Medical Institute - Al-Mansur, Middle Technical University, Iraq., S. S. Chiad, Department of Physics, College of Education, Mustansiriyah University, Baghdad, Iraq, N. F. Habubi, Department of Radiation and Sonar Technologies, Alnukhba University College, Iraq, Z. S. A. Mosa, Department of Pharmacy, Al-Manara College for Medical Science, Iraq, Y. H. Kadhim, Department of Optics Techniques, Al-Mustaqbal University College, Babylon, Iraq, M. Jadan, Department of Physics, College of Science, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, 31441 Dammam, Saudi Arabia

Abstract

TiO2 and TiO2:Cu films were deposited by spray pyrolysis (SP). X-ray diffraction reveals that deposited films have a polycrystalline structural. The AFM image of the surface reveals that roughness and root mean square affected by doping. Optical transmission of films was found to decrease from 94 % to 84 % with the as the doping percentage increase to 3. Optical bandgap (Eg) of TiO2 thin film was 3.947eV. The bandgap is shifted to lower energies upon doping.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: ZnO doping and properties · Copper-based nanomaterials and applications · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (52)

Show source-provided references
1. [1] Z. Wu, D. Yuan, S. Lin, W. Guo, D. Zhan, L. Sun, C. Lin,. Int. J. Hydrog. Energy, 45, 32012-32021 (2020);. https://doi.org/10.1016/j.ijhydene.2020.08.258.10.1016/j.ijhydene.2020.08.258 ↗
2. [2] J. Yu, J. Zou, P. Xu, Q. He, J. Clean. Prod. 251, 119744 (2020); https://doi.org/10.1016/j.jclepro.2019.119744.10.1016/j.jclepro.2019.119744 ↗
3. [3] S. K. Muhammad, E. S. Hassan, K. Y. Qader, K. H. Abass, S. S. Chiad, N. F. Habubi, Nano Biomedicine and Engineering, 12 (1), pp. 67-74, (2020); https://doi.org/10.5101/nbe.v12i1.p67-7410.5101/nbe.v12i1.p67-74 ↗
4. [4] S. S. Chiad, N. F. Habubi, W. H. Abass, M.H. Abdul-Allah, Journal of Optoelectronics and Advanced Materials, 18(9-10), 822-826, (2016).
5. [5] T. Hoseinzadeh, S. Solaymani, S. Kulesza, A. Achour, Z. Ghorannevis,, Ş. Ţălu, M. Bramowicz, M. Ghoranneviss, S. Rezaee, A. Boochani, N. Mozaffari., J. Electroanal. Chem., 830- 831, 80-87 (2018); https://doi.org/10.1016/j.jelechem.2018.10.037.10.1016/j.jelechem.2018.10.037 ↗
6. [6] X. Bao, H. Li, Z. Wang, F. Tong, M. Liu, Z. Zheng, P. Wang, H. Cheng, Y. Liu, Y. Dai, Y. Fan, Z. Li, Appl. Catal. B- Environ, 286, 119885 (2021); https://doi.org/10.1016/j.apcatb.2021.119885.10.1016/j.apcatb.2021.119885 ↗
7. [7] N. Y. Ahmed, B. A. Bader, M. Y. Slewa, N. F. Habubi, S. S. Chiad, NeuroQuantology, 18(6), 55-60 (2020); https://doi.org/10.14704/nq.2020.18.6.NQ2018310.14704/nq.2020.18.6.NQ20183 ↗
8. [8] E. S. Hassan, A.K. Elttayef, S.. Mostafa, M. H. Salim, S.S. Chiad, Journal of Materials Science: Materials in Electronics, 30 (17), 15943-15951, (2019); https://doi.1007/s10854-019-01954-110.1007/s10854-019-01954-1 ↗
9. [9] K. H. Jebur, N. J. Mohammed, Al-Mustansiriyah Journal of Science, 32(4), 60-66 (2021); http://doi.org/10.23851/mjs.v32i4.99310.23851/mjs.v32i4.993 ↗
10. [10] S. A. Hasan, J. A. Salman, S. S. Al-Jubori, Al-Mustansiriyah Journal of Science, 32(4), 21- 25 (2021); http://doi.org/10.23851/mjs.v32i4.103410.23851/mjs.v32i4.1034 ↗
11. [11] A. S. Alkelaby, K. H. Abass, T. H. Mubarak, N. F. Habubi, S. S. Chiad, I. Al-Baidhany, Journal of Global Pharma Technology 11(4), 347-352 (2019).
12. [12] N. Méndez-Lozano, M. Apátiga-Castro, A. Manzano-Ramírez, E. M. Rivera-Muñoz, R. Velázquez-Castillo, C. Alberto-González, M. Zamora-Antuñano, Results Phys., 16, 102891 (2020); https://doi.org/10.1016/j.rinp.2019.102891.10.1016/j.rinp.2019.102891 ↗
13. [13] W. Zhu, Y. Xu, H. Li, B. Dai, H. Xu, C. Wang, Y. Chao, H. Liu, Korean J. Chem. Eng., 31, 211-217 (2014); https://doi.org/10.1007/s11814-013-0224-3.10.1007/s11814-013-0224-3 ↗
14. [14] Y. Qian, J. Du, D. J. Kang, Microporous Mesoporous Mater, 273, 148-155 (2019); https://doi.org/10.1016/j.micromeso.2018.06.056.10.1016/j.micromeso.2018.06.056 ↗
15. [15] J.-i Fujisawa, Chem. Phys. Lett., 739, 136974 (2020); https://doi.org/10.1016/j.cplett.2019.136974.10.1016/j.cplett.2019.136974 ↗
16. [16] J. Mohapatra, M. Xing, J. Elkins, J. Ping Liu, J. Alloys Compd., 824, 153874 (2020); https://doi.org/10.1016/j.jallcom.2020.153874.10.1016/j.jallcom.2020.153874 ↗
17. [17] G.B. Soares, R.A.P. Ribeiro, S.R. de Lazaro, C. Ribeiro, N. RSC Adv., 6, 89687-89698 (2016); https://doi.org/10.1039/C6RA15825K.10.1039/C6RA15825K ↗
18. [18] O. Chibani, F. Challali, T. Touam, Opt. Eng., 58, 047101 (2019); https://doi.org/10.1117/1.OE.58.4.047101.10.1117/1.OE.58.4.047101 ↗
19. [19] R. Renugadevi, T. Venkatachalam, R. Narayanasamy, S. Dinesh Kirupha, Optik, 127, 10127- 10134 (2016), https://doi.org/10.1016/j.ijleo.2016.07.090.10.1016/j.ijleo.2016.07.090 ↗
20. [20] O. Banakh, P. E. Schmid, R. Sanjines,, F. Levy, Surf. Coat. Technol., 151-152, 272-275 (2002); https://doi.org/10.1016/S0257-8972(01)01605-X.10.1016/S0257-8972(01)01605-X ↗
21. [21] P. B. Nair, V. B. Justinvictor, G. P. Daniel, K. Joy, J. Mater. Sci.: Mater. Electron., 24, 2453- 2460 (2013), https://doi.org/10.1007/s10854-013-1117-2.10.1007/s10854-013-1117-2 ↗
22. [22] B. Gong, X. Luo, N. Bao, J. Ding, S. Li, J. Yi, Surf. Interface Anal., 46, 1043-1046 (2014); https://doi.org/10.1002/sia.5397.10.1002/sia.5397 ↗
23. [23] A. A. Z. Alaabedin, B. H. Hamza, A. Mu. Abdual-Majeed, S. F. Bamsaoud, Al-Mustansiriyah Journal of Science, 34 (3), 115-123 (2023); https://doi.org/10.23851/mjs.v34i3.133910.23851/mjs.v34i3.1339 ↗
24. [24] R. S. Dubey, S. Singh, Results Phys., 7, 1283-1288 (2017); https://doi.org/10.1016/j.rinp.2017.03.014.10.1016/j.rinp.2017.03.014 ↗
25. [25] T. K. Maity, S. L.Sharma, Bull. Mater. Sci., 31 (6) 841-846 (2008); https://doi.org/10.1007/s12034-008-0134-x10.1007/s12034-008-0134-x ↗
26. [26] X. Li, F. He, G. Liu, Y. Huang, C. Pan, C. Guo, Materials Letters, 67 369-372 (2012); https://doi.org/10.1016/j.matlet.2011.09.11110.1016/j.matlet.2011.09.111 ↗
27. [27] X. He, C. P. Yang, G. L. Zhang, D. W. Shi, Q. A. Huang, H. B. Xiao, Y. Liu, R. Xiong, Mater. Des. 106, 74-80 (2016); https://doi.org/10.1016/j.matdes.2016.05.025.10.1016/j.matdes.2016.05.025 ↗
28. [28] E. S. Hassan, K. Y. Qader, E. H. Hadi, S. S. Chiad, N. F. Habubi, K. H. Abass, Nano Biomedicine and Engineering, 12(3), pp. 205-213 (2020); https://doi.org/10.5101/nbe.v12i3.p205-21310.5101/nbe.v12i3.p205-213 ↗
29. [29] Khadayeir, A. A., Hassan, E. S., Mubarak, T. H., Chiad, S.S., Habubi, N. F., Dawood, M.O., Al-Baidhany, I. A., Journal of Physics: Conference Series, 1294 (2) 022009( 2019 ); https://doi.1088/1742-6596/1294/2/02200910.1088/1742-6596/1294/2/022009 ↗
30. [30] M. D. Sakhil, Z. M. Shaban, K. S. Sharba, N. F. Habub, K. H. Abass, S. S. Chiad, A. S. Alkelaby, NeuroQuantology, 18 (5), 56-61 (2020); https://doi.org/10.14704/nq.2020.18.5.NQ2016810.14704/nq.2020.18.5.NQ20168 ↗
31. [31] E. H. Hadi, D. A. Sabur, S. S. Chiad, N. F. Habubi, K., Abass, Journal of Green Engineering, 10 (10), 8390-8400 (2020); https://doi.org/10.1063/5.009516910.1063/5.0095169 ↗
32. [32] Hassan, E.S., Mubarak, T.H., Chiad, S.S., Habubi, N.F., Khadayeir, A.A., Dawood, M.O., AlBaidhany, I. A. , Journal of Physics: Conference Series, 1294(2), 022008 (2019 ); https://doi.1088/1742-6596/1294/2/02200810.1088/1742-6596/1294/2/022008 ↗
33. [33] M. S. Othman, K. A. Mishjil, H. G. Rashid, S. S. Chiad, N. F. Habubi, I. A. Al-Baidhany, Journal of Materials Science: Materials in Electronics, 31(11), 9037-9043 (2020); https://doi.org/10.1007/s10854-020-03437-010.1007/s10854-020-03437-0 ↗
34. [34] N. N. Jandow, M. S. Othman, N. F.Habubi, S. S. Chiad, K. A. Mishjil, I. A. Al-Baidhany, Materials Research Express, 6 (11), (2020); https://doi.org/10.1088/2053-1591/ab4af810.1088/2053-1591/ab4af8 ↗
35. [35] H. T. Salloom, E. H. Hadi, N. F. Habubi, S. S. Chiad, M. Jadan, J. S. Addasi, Digest Journal of Nanomaterials and Biostructures, 15 (4), 189-1195 (2020); https://doi.org/10.15251/DJNB.2020.154.118910.15251/DJNB.2020.154.1189 ↗
36. [36] A. J. Ghazai, O. M. Abdulmunem, K. Y. Qader, S. S. Chiad, N. F. Habubi, AIP Conference Proceedings 2213 (1), 02010 1(2020); https://doi.org/10.1063/5.000015810.1063/5.0000158 ↗
37. [37] J. C. González-Torres, L. A. Cipriano, E. Poulain, V. Domínguez-Soria, R. García-Cruz, O. Olvera-Neria, J. Mol. Model., 24, 1-11 (2018); https://doi.org/10.1007/s00894-018-3816-3.10.1007/s00894-018-3816-3 ↗
38. [38] H. A. Hussin, R. S. Al-Hasnawy, R. I. Jasim, N. F. Habubi, S. S. Chiad, Journal of Green Engineering, 10(9), 7018-7028 (2020); https://doi.org/10.1088/1742-6596/1999/1/01206310.1088/1742-6596/1999/1/012063 ↗
39. [39] S. S. Chiad, H. A. Noor, O. M. Abdulmunem, N. F. Habubi, M. Jadan, J. S. Addasi, Journal of Ovonic Research, 16 (1), 35-40 (2020).10.15251/JOR.2020.161.35 ↗
40. [40] A. A. Khadayeir, R. I. Jasim, S. H. Jumaah, N. F, Habubi, S. S. Chiad, Journal of Physics: Conference Series,1664 (1) (2020); https://doi.org/10.1088/1742-6596/1664/1/01200910.1088/1742-6596/1664/1/012009 ↗
41. [41] S. Bhat, K. M. Sandeep, P. Kumar, S. M. Dharmaprakash, K. Byrappa, J. Mater. Sci.: Mater. Electron., 29, 1098-1106 (2018); https://doi.org/10.1007/s10854-017-8011-2.10.1007/s10854-017-8011-2 ↗
42. [42] Qader, K.Y., Ghazi, R.A., Jabbar, A.M., Abass, K.H., Chiad, S.S., Reduce of energy gap of CuO nano structure film by Ag doping, Journal of Green Engineering, 10(10), pp. 7387-7398, 2020.
43. [43] Chiad, S.S., Noor, H.A., Abdulmunem, O.M., Habubi, N.F., Journal of Physics: Conference Series 1362(1), 012115 (2019); https://doi.org/10.1088/1742-6596/1362/1/01211510.1088/1742-6596/1362/1/012115 ↗
44. [44] R. S Ali, N. A. H. Al Aaraji, E. H. Hadi, N. F. Habubi, S. S. Chiad, Journal of Nanostructuresthis link is disabled, 10(4), 810-816 (2020); https://doi: 10.22052/jns.2020.04.014
45. [45] M. M. Momenin, Y. Ghayeb, Ceram. Int., 42, 7014-7022 (2016); https://doi.org/10.1016/j.ceramint.2016.01.089.10.1016/j.ceramint.2016.01.089 ↗
46. [46] R. S. Ali, M. K. Mohammed, A. A. Khadayeir, Z. M. Abood, N. F. Habubi and S. S. Chiad, Journal of Physics: Conference Series, 1664 (1), 012016 (2020); https://doi:10.1088/1742-6596/1664/1/01201610.1088/1742-6596/1664/1/012016 ↗
47. [47] M.O. Dawood, S.S. Chiad, A.J. Ghazai, N.F. Habubi, O.M. Abdulmunem, AIP Conference Proceedings 2213, 020102,(2020); https://doi.org/10.1063/5.000013610.1063/5.0000136 ↗
48. [48] R. S. Ali, H. S. Rasheed, N. F. Habubi, S.S. Chiad, Chalcogenide Letters, 20(1), pp. 63-72 (2023); https://doi.org/10.15251/CL.2023.201.6310.15251/CL.2023.201.63 ↗
49. [49] M. M. Khalaf, H. M. A. El-Lateef, H. M. Ali, Plasmonics, 13, 1795-1802 (2018); https://doi.org/10.1007/s11468-018-0693-7.10.1007/s11468-018-0693-7 ↗
50. [50] A. A. Khadayeir, E. S. Hassan, S. S. Chiad, N. F. Habubi, K. H. Abass, M. H. Rahid, T. H. Mubarak, M. O. Dawod, and I.A. Al-Baidhany, Journal of Physics: Conference Series 1234 (1), 012014, (2019); https://doi.1088/1742-6596/1234/1/01201410.1088/1742-6596/1234/1/012014 ↗
51. [51] N. N. Jandow, N. F. Habubi, S. S. chiad, I. A. Al-Baidhany and M. A. Qaeed, International Journal of Nanoelectronics and Materials, 12 (1), 1-10 2019.
52. [52] J. Tian, H. Deng, L. Sun, H. Kong, P. Yang, J. Chu, Thin Solid Films, 520, 5179-5183 (2012); https://doi.org/10.1016/j.tsf.2012.03.12510.1016/j.tsf.2012.03.125 ↗