DataVXDigest Journal of Nanomaterials and BiostructuresPaper
journal article·2025-07-15Open access

Organic ultraviolet photodetectors based on subphthalocyanine derivatives

School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, L. Zhou, F. Ma, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, G. Zhang, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, J. Tian, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, Y. Zhang, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, J. Zhao, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, B. Hu, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384

Digest Journal of Nanomaterials and Biostructures· Volume 20· Issue 2
Publisher pageOpen full text
Source abstract

Abstract

In this article, four subphthalocyanine (SubPc) derivatives were synthesized and characterized. These materials exhibit strong ultraviolet (UV) absorption and excellent donor properties, as confirmed by photophysical and electrochemical characterization. Solution-processed UV photodetectors incorporating SubPc 3a (shown in Scheme 1) as the active layer demonstrate outstanding performance, achieving an external quantum efficiency (EQE) of 38.76 % and a specific detectivity (D*) of 2.18×1012 Jones. This work provides valuable insights into structure-property relationships of SubPc derivatives and advances their application in UV detection technologies.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Porphyrin and Phthalocyanine Chemistry · Photochromic and Fluorescence Chemistry · Organic Chemistry Cycloaddition Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (22)

Show source-provided references
1. [1] H. Chen, K. Liu, L. Hu, A.A. Al-Ghamdi, X. Fang, Mater. Today 18, 493 (2015); https://doi.org/10.1016/j.mattod.2015.06.00110.1016/j.mattod.2015.06.001 ↗
2. [2] A. F. McKinlay, Health Phys. 87, 171 (2004); https://doi.org/10.1097/00004032-200408000-0000610.1097/00004032-200408000-00006 ↗
3. [3] A. Hosseini, M. Abrari, S. S. Malvajerdi, S. M. Mohseni, H. D. Sun, M. Ghanaatshoar, ACS Appl. Mater. Interfaces 6, 22036 (2023); https://doi.org/10.1021/acsanm.3c0421810.1021/acsanm.3c04218 ↗
4. [4] X. Y. Zhou, Z. H. Lu, L. C. Zhang, Q. Q. Ke, Nano Energy 117, 108908 (2023); https://doi.org/10.1016/j.nanoen.2023.10890810.1016/j.nanoen.2023.108908 ↗
5. [5] M. H. Jia, L. B. Tang, K. S. Teng, Y. F. Lü, Appl. Surf. Sci. 643, 158641 (2023); https://doi.org/10.1016/j.apsusc.2023.15864110.1016/j.apsusc.2023.158641 ↗
6. [6] D. Bhat, S. Sahoo, J. Bhattacharyya, D. Ray. Org. Electron. 87, 105975 (2020); https://doi.org/10.1016/j.orgel.2020.10597510.1016/j.orgel.2020.105975 ↗
7. [7] D. Shao, W. Zhu, X. Liu, M. Li, J. Chen, Y.-Y. Sun, G. Xin, J. Lian, S. Sawyer, ACS Appl. Mater. Interfaces 12, 43106 (2020); https://doi.org/10.1021/acsami.0c0989010.1021/acsami.0c09890 ↗
8. [8] Y. Bernhard, P. Richard, R. A. Decréau, Tetrahedron 74, 1047 (2018);https://doi.org/10.1016/j.tet.2018.01.02910.1016/j.tet.2018.01.029 ↗
9. [9] P. J. Swarts, J. Conradie, Inorg. Chem. 59,7444 (2020); https://doi.org/10.1021/acs.inorgchem.0c0015010.1021/acs.inorgchem.0c00150 ↗
10. [10] C. G. Claessens, D. Gonzalez-Rodriguez, T. Torres, Chem. Rev. 102, 835 (2002); https://doi.org/10.1021/cr010145410.1021/cr0101454 ↗
11. [11] W. Li, D. Li, G. Dong, L. Duan, J. Sun, D. Zhang, L. Wang, Laser Photonics Rev. 10, 473 (2016); https://doi.org/10.1002/lpor.20150027910.1002/lpor.201500279 ↗
12. [12] G. E. Morse, M. G. Helander, J. F. Maka, Z. H. Lu, T. P. Bender, ACS Appl. Mater. Interfaces 2, 1934 (2010); https://doi.org/10.1021/am100260310.1021/am1002603 ↗
13. [13] M. G. Helander, G. E. Morse, J. Qiu, J. S. Castrucci, T. P. Bender, Z. H. Lu, ACS Appl. Mater. Interfaces 2, 3147 (2010); https://doi.org/10.1021/am100632y10.1021/am100632y ↗
14. [14] T. Kawata, Y. Chino, N. Kobayashi, M. Kimura, Langmuir 34, 7294 (2018); https://doi.org/10.1021/acs.langmuir.8b0111810.1021/acs.langmuir.8b01118 ↗
15. [15] C. E. Mauldin, C. Piliego, D. Poulsen, D. A. Unruh, C. Woo, B. Ma, J. L. Mynar, J. M. J. Fr'echet, ACS Appl. Mater. Interfaces 2, 2833 (2010); https://doi.org/10.1021/am100516a10.1021/am100516a ↗
16. [16] P. J. Swarts, J. Conradie, Electrochim. Acta. 329, 135165 (2020); https://doi.org/10.1016/j.electacta.2019.13516510.1016/j.electacta.2019.135165 ↗
17. [17] F. Ma, G. Zhang, X. Wu, W. Qu, Z. Sun, X. Li, X. Yin, J. Phys. Chem. C 126, 13496 (2022); https://doi.org/10.1021/acs.jpcc.2c0423210.1021/acs.jpcc.2c04232 ↗
18. [18] Y. Wang, L. Zhu, T. Wang, Y. Hu, Z. Deng, Q. Cui, Z. Lou, Y. Hou, F. Teng, Org. Electron. 62, 448 (2018); https://doi.org/10.1016/j.orgel.2018.08.01710.1016/j.orgel.2018.08.017 ↗
19. [19] X. Xu, X. Zhou, K. Zhou, Y. Xia, W. Ma, O. Inganäs, Adv. Funct. Mater. 28, 1805570 (2018); https://doi.org/10.1002/adfm.20180557010.1002/adfm.201805570 ↗
20. [20] S. S. Maklakov, T. V. Dubinina, M. M. Osipova, E. F. Petrusevich, A. D. Mishin, L. G. Tomilova, J. Porphyr. Phthalocya. 20, 1 (2016); https://doi.org/10.1142/S108842461650075910.1142/S1088424616500759 ↗
21. [21] D. González-Rodríguez, T. Torres, E. L. G. Denardin, D. Samios, V. Stefani, D. S. Correa, J. Organomet. Chem. 694, 1617 (2009); https://doi.org/10.1016/j.jorganchem.2008.10.05510.1016/j.jorganchem.2008.10.055 ↗
22. [22] I. A. Skvortsov, U. P. Kovkova, Y. A. Zhabanov, I. A. Khodov, N. V.Somov, G. L. Pakhomov, P. A. Stuzhin, Dyes and Pigments 185, 108944 (2021); https://doi.org/10.1016/j.dyepig.2020.10894410.1016/j.dyepig.2020.108944 ↗