DataVXDigest Journal of Nanomaterials and BiostructuresPaper
journal article·2023-12-04Open access

Enhanced high performance of aluminum/indium Co-doped lithium nickel manganese cobalt oxide for possible batteries application

Department of Physics, Faculty of Education for Girls, University of Kufa, Kufa, Iraq, S. R. Kadum, A. S. Baron, Department of Physics, Faculty of Science, University of Kufa, Kufa, Iraq, H. M. J. Haider, Department of Physics, Faculty of Education for Girls, University of Kufa, Kufa, Iraq

Digest Journal of Nanomaterials and Biostructures· Volume 18· Issue 4
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Abstract

In this study, the Li[Li0.20Ni0.13Co0.13-yMn0.54-x]AlyInxO2 was synthesized via sol-gel method. electrochemical and structural attributes of nanopowders determined by the thermal analysis (TGA)/(DTA), structural analysis (XRD), (FESEM), chemical analysis (EDS) and (FTIR), BET analysis and their results appraised. X-ray diffraction analysis were performed to study the formation of nanopowders, illustrating the α- NaFeO2 structure with R¯3m space group. FESEM Figures showed that the nanopowders have a group of the cubic and the hexagonal particles. Chemical test of the EDS proved the existence of Aluminum and Indium. TGA/DTA tests for the displayed weight loss in the nanopowders. Infrared spectroscopy studied connectivity bonds and chemical elements that are utilized in the cathode. The powders with Al (y = 0.02) and In (x = 0. 01) represented the high cycling efficiency and have better discharge capacity. Li[Li0.20Ni0.13Co0.13-0.02Mn0.54-0.01]Al0.02In0.01O2 displayed the higher cycling consistency and the better capacity in collation with those of the nonreplacement powders. Electrochemical impedance spectroscopy (EIS) showed that adding the Indium-Aluminum impurities improved the electrochemical efficiency of the Li[Li0.20Ni0.13Co0.13Mn0.54]O2.
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Research context

Energy storageNanomaterials

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

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References (34)

Show source-provided references
1. [1] Song, MK. Park, S. Alamgir, FM. Cho, J. Liu, M. Mater Sci Eng. 72, 203-252 (2011); https://doi.org/10.1016/j.mser.2011.06.00110.1016/j.mser.2011.06.001 ↗
2. [2] Donghan, K. Jason, RC. Michael, MT. Electrochem Commun 36,103-106 (2013).
3. [3] Li, L. Song, BH. Chang, YL. Xia, H. Yang, JR. Lee, KS. Lu, L. Power Sources 283,162-170 (2015); https://doi.org/10.1016/j.jpowsour.2015.02.08510.1016/j.jpowsour.2015.02.085 ↗
4. [4] Li L, Song B, Chang Y, Xia H, Yang J, Lee K, Lu L, power Sources 283, 162-170 (2015); https://doi.org/10.1016/j.jpowsour.2015.02.08510.1016/j.jpowsour.2015.02.085 ↗
5. [5] Zhao J, Wang Z, Guo H, Li X, He Z, Li, Ceram Int 41, 11396-11401 (2015); https://doi.org/10.1016/j.ceramint.2015.05.10210.1016/j.ceramint.2015.05.102 ↗
6. [6] He Z, Wang Z, Cheng L, Zhu Z, Li T, Li X, Guo H, Adv Powder Technol 25, 647-653 (2014).
7. [7] Song B, Lai MO, Lu L, "Influence of Ru, Electrochim Acta 80 187-195 (2012).
8. [8] Wang D, Huang Y, Huo Z, Chen L, Electrochim Acta 107 461-466 (2013); https://doi.org/10.1016/j.electacta.2013.05.14510.1016/j.electacta.2013.05.145 ↗
9. [9] Li Q, Li G, Fu C, Luo D, Fan J, Li L, ACS Appl Mater Interfaces, 6 10330-10341 (2014); https://doi.org/10.1021/am501764910.1021/am5017649 ↗
10. [10] Du J, Shan Z, Zhu K, Liu X, Tian J, Du H, J Solid State Electrochem 19, 1037-1044 (2015); https://doi.org/10.1007/s10008-014-2706-610.1007/s10008-014-2706-6 ↗
11. [11] Du K, Yang F, Hu G-r, Peng Z-d, Cao Y-b, Ryu KS, Power Sources 244, 29-34, (2013); https://doi.org/10.1016/j.jpowsour.2013.04.15210.1016/j.jpowsour.2013.04.152 ↗
12. [12] Aurbach D, Srur-Lavi O, Ghanty C, Dixit M, Haik O, Talianker M, Electrochem Soc 162, 1014-1027 (2015); https://doi.org/10.1149/2.0681506jes10.1149/2.0681506jes ↗
13. [13] Zhao, J. Wang, Z. Guo, H. Li, X. He, Z. Li, T. Ceram Int. 41, 11396-11401 (2015); https://doi.org/10.1016/j.ceramint.2015.05.10210.1016/j.ceramint.2015.05.102 ↗
14. [14][ He, Z. Wang, Z. Cheng, L. Zhu, Z. Li, T. Li, X. Guo, H. Adv Powder Technol 25, 647-653 (2014).10.1016/j.apt.2013.10.008 ↗
15. [15] Song, B. Lai, MO. Lu, L. Electrochim Acta 80, 187-195 (2012); https://doi.org/10.1016/j.electacta.2012.06.11810.1016/j.electacta.2012.06.118 ↗
16. [16] Dan, W. Yan, H. Zhenqing, H. Li, C. Electrochim Acta 107, 461-466 (2013); https://doi.org/10.1016/j.electacta.2013.05.14510.1016/j.electacta.2013.05.145 ↗
17. [17] Li, Q. Li, G. Fu, C. Luo, D. Fan, J. Li, L. ACS Appl Mater Interfaces 6, 10330-10341 (2014); https://doi.org/10.1021/am501764910.1021/am5017649 ↗
18. [18] Jiangyong, D. Zhongqiang, S. Kunlei, Z. Xiaoyan, L. Jianhua, T. Haiyan, D. Solid State Electrochem 19 1037-1044 (2015).
19. [19] Ke, D. Fei, Y. GR, H. Peng, ZD. Cao, YB. Kwang, SR. Power Sources 244 29-34, (2013).
20. [20] Hao, WJ. Zhan, HH. Chen, H. Wang, YH. Tan ,QQ. Su, FB. Particuology. 33, (2013).
21. [21] Johnson, C. Kim, J. Lefief, C. Li, N. Vaughey, J. Thackeray, M. Electrochem Commun. 6, 1085-1091 (2004); https://doi.org/10.1016/j.elecom.2004.08.00210.1016/j.elecom.2004.08.002 ↗
22. [22] Aurbach, D. Srur-Lavi, Ghanty, O. et al. Electrochem. Soc. 162 A1014-A1017 (2015).
23. [23] Ngala, J.K. Chernova, A.N. Ma, M. Mamak, M. Zavalij, P.Y. Whittingham, M.S. Mater. Chem. 14, 214-220 (2004); https://doi.org/10.1039/b309834f10.1039/b309834f ↗
24. [24] Na, SH. Kim, HO. Moon, CI. Mater Sci Forum. 486, 614-617 (2005); https://doi.org/10.4028/www.scientific.net/MSF.486-487.61410.4028/www.scientific.net/MSF.486-487.614 ↗
25. [25] Jiang, KC. Xin, S. Lee, JS. Kim, J. Xiao, XL. Guo, YG. Phys Chem. 14 2934-2939 (2012); https://doi.org/10.1039/c2cp23363k10.1039/c2cp23363k ↗
26. [26] Wen, L. Miao, W. Xing, LG. et al. Alloys and Compounds 543, 181-188 (2012).10.1016/j.jallcom.2012.07.074 ↗
27. [27] Cheng, C X. Tan, L. Liu, H. W. and Huang, X T. Mater Res Bull. 46, 2032-2038 (2011).
28. [28] D. Q. Liao, C. Y. Xia, X. M. Xi, Sol-Gel Science and Technology, 78 403-408 (2016); https://doi.org/10.1007/s10971-016-3956-910.1007/s10971-016-3956-9 ↗
29. [29] G. F, Xu, J. L. Li, Q. R. Xue, Power Sources 248 894-902 (2014).
30. [30] Tang, T. Zhang, HL, Electrochim Acta, 191 263-269 (2016); https://doi.org/10.1016/j.electacta.2016.01.14910.1016/j.electacta.2016.01.149 ↗
31. [31] A. Li, D. Ohsawa, Y, Power Sources, 183 344-349 (2008); https://doi.org/10.1016/j.jpowsour.2008.04.08610.1016/j.jpowsour.2008.04.086 ↗
32. [32] Li X, Kehui Q, Yuyan G, Xia H, Fangdong Z, Mater Sci 50 2914-2920 (2015); https://doi.org/10.1007/s10853-015-8856-910.1007/s10853-015-8856-9 ↗
33. [33] Huang Y, Jin FM, Chen FJ, Chen L, Power Sources 256 1-7 (2014); https://doi.org/10.1016/j.jpowsour.2014.01.08010.1016/j.jpowsour.2014.01.080 ↗
34. [34] Bangbang N, Jianling L, Yanying L, Zhanyu L, Zhe Y. Ceramics International 45 12484- 12494 (2019).