Luminescence, spectroscopic and electrochemical studies on halogen-based thulium compound: TmCl3
Source abstract
Abstract
Rare earth thulium tri chloride (TmCl3) has consistent distribution of brick shaped, rectangular particles with monoclinic crystal structure and 92 nm crystallite size. Density of dislocation is 1.181 × 1014m-2 . The calculated strain is 3.788 × 10−4 . The refractive index is 3.067, and the energy gap is 5.26 eV. Optical studies on TmCl3 assigns energy level transitions. Low-temperature magnetic studies upto 20K have revealed intriguing phase transitions between 50 and 99K which may be paramagnetic to antiferromagnetic transition. Investigation of aqueous solution of TmCl3 exhibits wider potential window 2.86V indicating electrochemically superior nature of the electrolyte.
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Research context
OpenAlex topics: Luminescence Properties of Advanced Materials · Inorganic Fluorides and Related Compounds · Solid-state spectroscopy and crystallography
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References (48)
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