journal article·2021-12Open access

Fabrication of Fe2CuO4 nanoparticles via photolysis technique for improved performance in dye-sensitized solar cells

Department of Chemistry, College of Science, Mustansiriyah University, Baghdad, Iraq, A. F. Kamil, H. I. Abdullah, Department of Chemistry, College of Science, Mustansiriyah University, Baghdad, Iraq, A. M. Rheima, Department of Chemistry, College of Science, University of Wasit, kut, Iraq, S. H. Mohammed, Department of Chemistry, College of education, University of Garmian, kalar, Iraq, S. J. Tumaa, Department of Chemistry, College of Science, University of Wasit, kut, Iraq, R. M. Abed, Department of Chemistry, College of Science, University of Wasit, kut, Iraq

Abstract

This paper created excellent photo-anode materials based on Fe2CuO4 Nanoparticles to efficiently convert the photoelectric into a dye-sensitized solar cell (DSSC). The Fe2CuO4 nanoparticles were prepared via the UV-Irradiation method. The synthesized nanoparticles morphology structure and optical properties were examined using various X-ray diffraction (XRD), Energy Dispersive X-Ray Analysis (EDX) / mapping, field emission scanning electron microscope (FE-SEM), Transmission Electron Microscopy (TEM), and photoluminescence spectroscopy (PL) are examples of these techniques. Transmission electron microscopes (TEM) images validated the Field emission scanning electron microscopy (FE-SEM) and crystal structure of the generated Fe2CuO4 NPs, which had an average particle size of (11.7 nm), and the X-ray diffraction analysis (XRD) investigation indicated no impurity peaks. Photoluminescence spectroscopy (PL) was used to examine the optical characteristics, and the energy gap was found to be 1.95 eV. Nano-powder has been used to develop a successful photo-sensitizing solar cell employing cibacron brilliant red b as a photosensitizer with an efficiency of about 6.47 to 10.39 % energy conversion. We have created a time-saving technology that is simple to regulate, which makes it possible to produce nano-particulate composites without a high testing need. Our findings could investigate an opportunity for nanomaterials to be synthesized with highly rapid answers and now photoanode.
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Research context

OpenAlex topics: Iron oxide chemistry and applications · TiO2 Photocatalysis and Solar Cells · Pigment Synthesis and Properties

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