journal article·2022-01

Shedding Light on Functional Hybrid Nanocomposites 19th Century Paint Medium

Hélène Pasco, Laurence de Viguerie, Marco Faustini, Cristina Coelho‐Diogo, Ovidiu Ersen, Christel Gervais, Frédéric Gobeaux, Dris Ihiawakrim, Maguy Jaber, Philippe Walter, Clément Sanchez

Advanced Functional Materials· Volume 32· Issue 4
Publisher page

Abstract

Abstract British 19th century painters formulated gelled systems often described as ideal paint mediums. These so‐called megilps or gumtions are based on common paint materials like linseed oil, lead acetate, and mastic resin, and allowed painters such as J.M.W Turner to improve their paint's properties and achieve unprecedented effects in an age of innovation. To propose a structural scheme of these hybrid systems of unprecedented complexity, it is paramount to design and study model systems using a broad combination of advanced spectroscopic techniques and microscopies. Through this approach, gel Mediums can be described as nanocomposites based on lead metallogels co‐existing with lead oxide nanoparticles and a partially polymerized fraction. These functional hybrid materials created a real breakthrough on 19th century paints performances.
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Research context

OpenAlex topics: Cultural Heritage Materials Analysis · Enhanced Oil Recovery Techniques · Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Sorbonne Université CNRS UMR 8220 LAMS 4 place Jussieu Paris cedex 05 75252 France

Sorbonne Université CNRS UMR 7574 Collège de France LCMCP 4 place Jussieu Paris cedex 05 75252 France

Sorbonne‐Université CNRS Institut des Matériaux de Paris‐Centre FR2482 Paris F‐75005 France

Institut de Physique et Chimie des Matériaux (IPCMS) UMR 7504 CNRS – Université de Strasbourg 23 rue du Loess, BP43 Strasbourg Cedex 2 67034 France

Université Paris‐Saclay CEA CNRS UMR 3685 Gif‐sur‐Yvette 91190 France

Chemistry of ultradivided matter USIAS Chair Université de Strasbourg Institut of Advanced Studies Strasbourg 67000 France

Funding

Agence Nationale de la Recherche

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