journal article·2016-10-14

Single-Ion Conducting Polymer Electrolytes for Lithium Metal Polymer Batteries that Operate at Ambient Temperature

Luca Porcarelli, Alexander S. Shaplov, Federico Bella, Jijeesh R. Nair, David Mecerreyes, Claudio Gerbaldi

ACS Energy Letters· Volume 1· Issue 4
Publisher page

Abstract

Safety issues rising from the use of conventional liquid electrolytes in lithium-based batteries are currently limiting their application to electric vehicles and large-scale energy storage from renewable sources. Polymeric electrolytes represent a solution to this problem due to their intrinsic safety. Ideally, polymer electrolytes should display both high lithium transference number ( t Li + ) and ionic conductivity. Practically, strategies for increasing t Li + often result in low ionic conductivity and vice versa. Herein, networked polymer electrolytes simultaneously displaying t Li + approaching unity and high ionic conductivity (σ ≈ 10 –4 S cm –1 at 25 °C) are presented. Lithium cells operating at room temperature demonstrate the promising prospect of these materials.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Applied Science and Technology (DISAT), Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS), Vavilov str. 28, 119991 Moscow, Russia

POLYMAT, University of the Basque Country UPV/EHU, Joxe Mari Korta Center, Avenida Tolosa 72, 20018 Donostia-San Sebastian, Spain

Funding

European Research Council · Russian Foundation for Basic Research · Directorate-General for Research and Innovation · Seventh Framework Programme

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