Nanoporous Solid-State Sensitization of Triplet Fusion Upconversion
Source abstract
Abstract
Photochemical upconversion of green to blue light is demonstrated in thin films of nanostructured alumina stained with a metalloporphyrin sensitizer. The pores of the structure are filled with emitter molecules in a concentrated solution, allowing efficient upconversion within the solid-state scaffold. The photon generation quantum yield is measured to be 9.4%, which is nearly 40% of what is possible with a diphenylanthracene emitter. These results show that high-efficiency upconversion is possible with solid-state sensitization within a nanostructured thin-film architecture.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Luminescence Properties of Advanced Materials · Radioactive element chemistry and processing · Radiation Detection and Scintillator Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
ARC Centre of Excellence in Exciton Science, School of Chemistry, UNSW Sydney, NSW 2052, Australia
ARC Centre of Excellence in Exciton Science, School of Physics, UNSW Sydney, NSW 2052, Australia
ARC Centre of Excellence in Exciton Science, School of Photovoltaic and Renewable Energy Engineering, UNSW Sydney, NSW 2052, Australia
Funding
Australian Research Council · University of New South Wales
References (45)
Show source-provided references
1. 10.1038/s41586-018-0835-210.1038/s41586-018-0835-2 ↗
2. 10.1039/C1CC16015J10.1039/C1CC16015J ↗
3. 10.1039/C4EE02481H10.1039/C4EE02481H ↗
4. 10.1039/D3QM00069A10.1039/D3QM00069A ↗
5. 10.1039/C1CS15187H10.1039/C1CS15187H ↗
6. 10.1038/s41586-022-04485-810.1038/s41586-022-04485-8 ↗
7. 10.1021/cr020357g10.1021/cr020357g ↗
8. 10.1146/annurev-physchem-092722-10495210.1146/annurev-physchem-092722-104952 ↗
9. 10.1016/j.ccr.2010.01.00310.1016/j.ccr.2010.01.003 ↗
10. 10.1039/C4CP03936J10.1039/C4CP03936J ↗
11. 10.1039/B913243K10.1039/B913243K ↗
12. 10.1021/jz100566u10.1021/jz100566u ↗
13. 10.1039/D1TC05659J10.1039/D1TC05659J ↗
14. 10.1016/j.ccr.2018.02.01110.1016/j.ccr.2018.02.011 ↗
15. 10.1002/adfm.20120128410.1002/adfm.201201284 ↗
16. 10.1039/D1MH01542G10.1039/D1MH01542G ↗
17. 10.1038/s41566-021-00904-w10.1038/s41566-021-00904-w ↗
18. 10.1038/nphoton.2015.22610.1038/nphoton.2015.226 ↗
19. 10.1016/j.matt.2019.05.02610.1016/j.matt.2019.05.026 ↗
20. 10.1515/zna-1949-050110.1515/zna-1949-0501 ↗
21. 10.1021/acs.jpclett.9b0105810.1021/acs.jpclett.9b01058 ↗
22. 10.1021/acsenergylett.1c0179410.1021/acsenergylett.1c01794 ↗
23. 10.1039/D2NR05767K10.1039/D2NR05767K ↗
24. 10.1039/C5CP04825G10.1039/C5CP04825G ↗
25. 10.1021/acsenergylett.6b0000110.1021/acsenergylett.6b00001 ↗
26. 10.1021/acs.jpcc.7b0700310.1021/acs.jpcc.7b07003 ↗
27. 10.1039/C7TA00317J10.1039/C7TA00317J ↗
28. 10.1021/acs.jpclett.8b0263510.1021/acs.jpclett.8b02635 ↗
29. 10.1021/acsenergylett.9b0087010.1021/acsenergylett.9b00870 ↗
30. 10.1021/jp209774p10.1021/jp209774p ↗
31. 10.1021/jp402477q10.1021/jp402477q ↗
32. 10.1021/acs.jpcc.5b0890710.1021/acs.jpcc.5b08907 ↗
33. 10.1021/jp511812910.1021/jp5118129 ↗
34. 10.1039/D0CP01735C10.1039/D0CP01735C ↗
35. 10.1039/C4TC02584A10.1039/C4TC02584A ↗
36. 10.1002/aenm.20120089710.1002/aenm.201200897 ↗
37. 10.1039/tf970660008010.1039/tf9706600080 ↗
38. 10.1038/s41566-020-0664-310.1038/s41566-020-0664-3 ↗
39. 10.1021/jz300012u10.1021/jz300012u ↗
40. 10.1088/1742-6596/185/1/01200210.1088/1742-6596/185/1/012002 ↗
41. 10.1103/PhysRevB.78.19511210.1103/PhysRevB.78.195112 ↗
42. 10.1021/acsenergylett.0c0115010.1021/acsenergylett.0c01150 ↗
43. 10.6028/jres.080A.03810.6028/jres.080A.038 ↗
44. 10.1021/j150571a00310.1021/j150571a003 ↗
45. 10.1039/C5TC02626A10.1039/C5TC02626A ↗