A New Strategy to Effectively Suppress the Initial Capacity Fading of Iron Oxides by Reacting with LiBH₄

In this work, a new facile and scalable strategy to effectively suppress the initial capacity fading of iron oxides is demonstrated by reacting with lithium borohydride (LiBH₄) to form a B‐containing nanocomposite. Multielement, multiphase B‐containing iron oxide nanocomposites are successfully prepared by ball‐milling Fe₂O₃ with LiBH₄, followed by a thermochemical reaction at 25–350 °C. The resulting products exhibit a remarkably superior electrochemical performance as anode materials for Li‐ion batteries (LIBs), including a high reversible capacity, good rate capability, and long cycling durability. When cycling is conducted at 100 mA g⁻¹, the sample prepared from Fe₂O₃–0.2LiBH₄ delivers an initial discharge capacity of 1387 mAh g⁻¹. After 200 cycles, the reversible capacity remains at 1148 mAh g⁻¹, which is significantly higher than that of pristine Fe₂O₃ (525 mAh g⁻¹) and Fe₃O₄ (552 mAh g⁻¹). At 2000 mA g⁻¹, a reversible capacity as high as 660 mAh g⁻¹ is obtained for the B‐containing nanocomposite. The remarkably improved electrochemical lithium storage performance can mainly be attributed to the enhanced surface reactivity, increased Li⁺ ion diffusivity, stabilized solid‐electrolyte interphase (SEI) film, and depressed particle pulverization and fracture, as measured by a series of compositional, structural, and electrochemical techniques.