journal article·2024-06

Recent advances in the hybrid cathode for rechargeable zinc-bromine redox batteries

Dabin Han, Sangaraju Shanmugam

Publisher page

Abstract

Rechargeable metal-bromine batteries have emerged as promising candidates to develop competitive, cost-effective, high-energy-density energy storage systems. The general configuration of a metal-bromine battery includes a metal anode and a bromine cathode. The emergence of zinc-bromine redox batteries (ZBRBs) is attributed to the earth's abundance of zinc, the cost-effectiveness of the active materials, and the high theoretical energy density. Recent advancements have highlighted using bromides (Br−, Br2, and Brn− (n = 3, 5, 7 …)) entrapping materials for the cathode to enhance the Br−/Br2 redox reaction and inhibit the Br2 diffusion in the ZBRBs. This review aims to explore the various arrangements and insights into bromides-entrapping-based cathodes recently reported. Finally, we share perspectives on the remaining challenges and prospects for the ZBRBs. © 2024 Elsevier B.V. ; FALSE ; scie ; scopus
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced battery technologies research · Advanced Battery Technologies Research · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (40)

Show source-provided references
1. Investment-based optimisation of energy storage design parameters in a grid-connected hybrid renewable energy system10.1016/j.apenergy.2023.122384 ↗
2. Joint operation of mobile battery, power system, and transportation system for improving the renewable energy penetration rate10.1016/j.apenergy.2023.122455 ↗
3. A zwitterionic composite membrane for a high-performance zinc/bromine flowless battery10.1039/D2TA04745D ↗
4. Lithium-ion battery supply Chain considerations: analysis of potential bottlenecks in critical metals10.1016/j.joule.2017.08.019 ↗
5. Effect of positive electrode modification on the performance of zinc-bromine redox flow batteries
6. Modulated Zn deposition by glass fiber interlayers for enhanced cycling stability of Zn-Br redox flow batteries10.1021/acssuschemeng.1c03796 ↗
7. Improved static membrane-free zinc-bromine batteries by an efficient bromine complexing agent
8. Suppression of self-discharge in a non-flowing bromine battery via in situ generation of countercharged groups
9. An ultra-low self-discharge Aqueous|Organic membraneless battery with minimized Br2 cross-over
10. Zinc–bromine rechargeable batteries: from device configuration, electrochemistry, material to performance evaluation10.1007/s40820-023-01174-7 ↗
11. Zinc–bromine rechargeable batteries: from device configuration, electrochemistry, material to performance evaluation10.1007/s40820-023-01174-7 ↗
12. High energy density electrolytes for H2/Br2 redox flow batteries, their polybromide composition and influence on battery cycling limits10.1039/D0RA10721B ↗
13. Achieving exceptional cell voltage (2.34 V) through tailoring pH of aqueous Zn-Br2 redox flow battery for potential large-scale energy storage10.1016/j.electacta.2022.141799 ↗
14. Scientific issues of zinc-bromine flow batteries and mitigation strategies
15. Zinc–bromine rechargeable batteries: from device configuration, electrochemistry, material to performance evaluation10.1007/s40820-023-01174-7 ↗
16. Advanced porous composite membrane with ability to regulate zinc deposition enables dendrite-free and high-areal capacity zinc-based flow battery10.1016/j.ensm.2022.02.034 ↗
17. Lamella-like electrode with high Br2-entrapping capability and activity enabled by adsorption and spatial confinement effects for bromine-based flow battery10.1016/j.scib.2022.05.012 ↗
18. Synthesis and characterization of highly durable hydrocarbon-based composite membrane for zinc-bromine redox flow battery10.1016/j.jpowsour.2023.232821 ↗
19. Active material crossover suppression with bi-ionic transportability by an amphoteric membrane for Zinc–Bromine redox flow battery10.1016/j.jpowsour.2022.231637 ↗
20. Metal-free fabrication of nitrogen-doped vertical graphene on graphite felt electrodes with enhanced reaction kinetics and mass transport for high-performance redox flow batteries
21. Current status and challenges for practical flowless Zn–Br batteries
22. In-situ N-rGO scaffold @3D graphite felt for high power polyhalide hybrid redox flow battery10.1002/admt.202200869 ↗
23. Low-dimensional nitrogen-doped carbon for Br2/Br− redox reaction in zinc-bromine flow battery
24. Nanocatalyzed PtNi alloy intact @3D graphite felt as an effective electrode for super power redox flow battery10.1002/admi.202202007 ↗
25. Metal oxide coatings on carbon electrodes with large mesopores for deeply charged zinc bromine redox flow batteries10.1149/2.1531910jes ↗
26. Low loading of Pt@Graphite felt for enhancing multifunctional activity towards achieving high energy efficiency of Zn–Br2 redox flow battery10.1016/j.jpowsour.2020.228912 ↗
27. Bi-layer graphite felt as the positive electrode for zinc-bromine flow batteries: achieving efficient redox reaction and stable mass transport
28. Sandwich-like multi-scale hierarchical porous carbon with a highly hydroxylated surface for flow batteries10.1039/D0TA10284A ↗
29. Boosting aqueous non-flow zinc-bromine batteries with a two-dimensional metal-organic framework host: an adsorption-catalysis approach10.1039/D3EE01639K ↗
30. A mesoporous tungsten oxynitride nanofibers/graphite felt composite electrode with high catalytic activity for the cathode in Zn-Br flow battery
31. Cluster-based crystalline materials for iodine capture
32. Covalent organic frameworks and their derivatives for better metal anodes in rechargeable batteries10.1021/acsnano.1c05497 ↗
33. Confining aqueous Zn-Br halide redox Chemistry by Ti3C2TXMXene10.1021/acsnano.0c09380 ↗
34. Multifunctional carbon felt electrode with N-rich defects enables a long-cycle zinc-bromine flow battery with ultrahigh power density10.1002/adfm.202102913 ↗
35. Modified viologen-assisted reversible bromine capture and release in flowless zinc–bromine batteries10.1016/j.cej.2023.142624 ↗
36. A polybromide confiner with selective bromide conduction for high performance aqueous zinc-bromine batteries10.1016/j.ensm.2022.03.052 ↗
37. Metallic Ti4O7 with strong polybromide chemisorption ability as polar host for zinc–bromine batteries10.1016/j.scriptamat.2023.115883 ↗
38. A high-performance COF-based aqueous zinc-bromine battery10.1016/j.cej.2022.138915 ↗
39. Aqueous zinc batteries with ultra-fast redox kinetics and high iodine utilization enabled by iron single atom catalysts10.1007/s40820-023-01093-7 ↗
40. High-energy efficiency membraneless flowless Zn–Br battery: utilizing the electrochemical–chemical growth of polybromides