Gating-out emission for fluorescence-free Raman spectra for the study of electrode interfaces
Source abstract
Abstract
Kerr-gated Raman spectroscopy is a powerful technique that can suppress the fluorescence emission signals and reveal the otherwise hidden Raman scattering information within a variety of Li-ion battery materials. Herein, recent advances in the analysis of battery materials both ex situ and operando via Kerr-gated Raman spectroscopy are described and an outlook for broader application of the technique in the study of electrochemical systems is discussed.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advancements in Battery Materials · Semiconductor materials and devices · Quantum Dots Synthesis And Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (50)
Show source-provided references
1. In situ Raman study on electrochemical Li intercalation into graphite10.1149/1.2043869 ↗
2. In situ Raman study of electrochemical lithium insertion into mesocarbon microbeads heat-treated at various temperatures10.1149/1.1837049 ↗
3. In situ characterization of a graphite electrode in a secondary lithium-ion battery using Raman microscopy10.1366/0003702991945650 ↗
4. In situ Raman study on single- and double-walled carbon nanotubes as a function of lithium insertion10.1002/smll.200500496 ↗
5. Studying lithium intercalation into graphite particles via in situ Raman spectroscopy and confocal microscopy10.1007/s10008-004-0563-4 ↗
6. In situ Raman study on reversible structural changes of graphite negative-electrodes at high potentials in LiPF6-based electrolyte solution10.1149/2.1301610jes ↗
7. Probing the evolution of surface chemistry at the silicon–electrolyte interphase via in situ surface-enhanced Raman spectroscopy10.1021/acs.jpclett.9b03284 ↗
8. Diagnostic studies of polyolefin separators in high-power Li-ion cells10.1149/1.1649233 ↗
9. The Formation mechanism of fluorescent metal complexes at the LixNi0.5Mn1.5O4−δ/carbonate ester electrolyte interface10.1021/ja5116698 ↗
10. The complex electrochemistry of graphite electrodes in lithium-ion batteries10.1016/S0378-7753(01)00586-9 ↗
11. Advanced in situ methods for the characterization of practical electrodes in lithium-ion batteries10.1016/S0378-7753(00)00447-X ↗
12. Elucidating structural transformations in LixV2O5 electrochromic thin films by multimodal spectroscopies10.1021/acs.chemmater.0c01478 ↗
13. In situ Raman microscopy of a single graphite microflake electrode in a Li+-Containing electrolyte10.1021/jp037015e ↗
14. Raman microspectrometry applied to the study of electrode materials for lithium batteries10.1021/cr800344k ↗
15. Kerr gated Raman spectroscopy of LiPF6 salt and LiPF6-based organic carbonate electrolyte for Li-ion batteries10.1039/C9CP02430A ↗
16. Review of fluorescence suppression techniques in Raman spectroscopy10.1080/05704928.2014.999936 ↗
17. Time-gated Raman spectroscopy – a review10.1088/1361-6501/abb044 ↗
18. Operando time-gated Raman spectroscopy of solid catalysts10.1039/D3CY00967J ↗
19. Insight into the effects of confined hydrocarbon species on the lifetime of methanol conversion catalysts10.1038/s41563-020-0800-y ↗
20. Understanding the dynamics of fluorescence emission during zeolite detemplation using time resolved photoluminescence spectroscopy10.1021/acs.jpcc.9b09050 ↗
21. Understanding the deactivation phenomena of small-pore Mo/H-SSZ-13 during methane dehydroaromatisation10.3390/molecules25215048 ↗
22. Kerr-gated time-resolved Raman spectroscopy of equine cortical bone tissue10.1117/1.1827605 ↗
23. Depth profiling of calcifications in breast tissue using picosecond Kerr-gated Raman spectroscopy10.1039/B614388A ↗
24. Raman spectroscopy of street samples of cocaine obtained using Kerr gated fluorescence rejection10.1039/b401091d ↗
25. Lithium insertion into graphitic carbon observed via operando kerr-gated Raman spectroscopy enables high state of charge diagnostics10.1021/acsenergylett.2c01120 ↗
26. Efficient rejection of fluorescence from Raman spectra using picosecond Kerr gating10.1366/0003702991945993 ↗
27. Fluorescence suppression in resonance Raman spectroscopy using a high-performance picosecond Kerr gate10.1002/jrs.784 ↗
28. Fluorescence background suppression in Raman spectroscopy using combined Kerr gated and shifted excitation Raman difference techniques10.1002/jrs.840 ↗
29. Ultra: a unique instrument for time-resolved spectroscopy10.1366/000370210793561673 ↗
30. Polarization selectivity in time-resolved transient phase grating10.1016/0030-4018(87)90186-6 ↗
31. Operando Raman spectroscopy measurements of a high-voltage cathode material for lithium-ion batteries10.1021/acs.analchem.8b05819 ↗
32. Improved operando Raman cell configuration for commercially-sourced electrodes in alkali-ion batteries10.1149/1945-7111/ac132d ↗
33. In situ Raman study of lithium-ion intercalation into microcrystalline graphite10.1039/C4FD00079J ↗
34. Operando investigation into dynamic evolution of cathode–electrolyte interfaces in a Li-ion battery10.1021/acs.nanolett.9b00179 ↗
35. Microparticle electrodes and single particle microbatteries: electrochemical and in situ MicroRaman spectroscopic studies10.1021/ar300210q ↗
36. The origin of impedance rise in Ni-Rich positive electrodes for lithium-ion batteries10.1016/j.jpowsour.2021.229885 ↗
37. Development of a method for direct elemental analysis of lithium ion battery degradation products by means of total reflection X-ray fluorescence10.1016/j.sab.2015.08.005 ↗
38. Quantifying changes to the electrolyte and negative electrode in aged nmc532/graphite lithium-ion cells10.1149/2.0721811jes ↗
39. Visualizing ion diffusion in battery systems by fluorescence microscopy: a case study on the dissolution of LiMn2O410.1016/j.nanoen.2017.12.036 ↗
40. Visualisation of electrochemical processes by coupled electrochemistry and fluorescence microscopy
41. Initial stages of thermal decomposition of LiPF6-based lithium ion battery electrolytes by detailed Raman and NMR spectroscopy10.1039/c3ra42611d ↗
42. Direct operando observation of double layer charging and early solid electrolyte interphase formation in Li-ion battery electrolytes10.1021/acs.jpclett.0c01089 ↗
43. Unraveling the nanoscale heterogeneity of solid electrolyte interphase using tip-enhanced Raman spectroscopy10.1016/j.joule.2019.05.026 ↗
44. Effects of solute–solvent hydrogen bonding on nonaqueous electrolyte structure10.1021/acs.jpclett.5b01216 ↗
45. In situ Raman studies of graphite surface structures during lithium electrochemical intercalation10.1149/1.1838343 ↗
46. Graphite surface disorder detection using in situ Raman microscopy10.1016/j.ssi.2006.03.032 ↗
47. Assessment of recombinant protein production in E. coli with time-gated surface enhanced Raman spectroscopy (TG-SERS)10.1038/s41598-020-59091-3 ↗
48. Simultaneous surface-enhanced Raman scattering with a Kerr gate for fluorescence suppression10.1021/acs.jpclett.3c02926 ↗
49. Dynamics of solid-electrolyte interphase formation on silicon electrodes revealed by combinatorial electrochemical screening10.1002/anie.202207184 ↗
50. Differentiating between ion transport and plating–stripping phenomena in magnesium battery electrolytes using operando Raman spectroscopy10.1021/acsenergylett.3c00279 ↗