Bowtie‐Shaped NiCo₂O₄ Catalysts for Low‐Temperature Methane Combustion

Abstract Bowtie‐shaped NiCo₂O₄ nanostructures are prepared using a hydrothermal method. Variation of the synthesis parameters, including reaction time, additives, and calcination temperature, allows an understanding of the origin of the bowtie‐shaped structure to be developed. Methane oxidation experiments performed using temperature‐programed oxidation (TPO) show that the new materials, which do not contain precious metals, have excellent activity for low‐temperature methane combustion, with 100% conversion at ≈410 °C (gas hourly space velocity (GHSV): 90 000 mL (STP) g⁻¹ h⁻¹). The structure–activity relationships of the bowtie‐shaped nanostructures are explored.