journal article·2025-06

Cation effects in electrochemical CO2 reduction

Adnan Ozden, Yanwei Lum

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Ionic liquids properties and applications · Advanced Thermoelectric Materials and Devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Improving the operational stability of electrochemical CO2 reduction reaction via salt precipitation understanding and management
2. Kilowatt-scale tandem CO2 electrolysis for enhanced acetate and ethylene production10.1038/s44286-024-00076-8 ↗
4. Improved CO selectivity via anion exchange membrane electrode assembly-type CO2 electrolysis with an ionomer-coated Zn-based cathode10.1155/2024/8984734 ↗
5. Carbon dioxide electrolysis systems for high carbon efficiency10.1016/j.enconman.2024.119443 ↗
6. Ampere-level CO2 electroreduction with single-pass conversion exceeding 85% in acid over silver penetration electrodes10.1038/s41467-024-50521-8 ↗
7. Conversion of CO2 to multicarbon products in strong acid by controlling the catalyst microenvironment
8. Efficient multicarbon formation in acidic CO2 reduction via tandem electrocatalysis10.1038/s41565-023-01543-8 ↗
9. Carbon-efficient carbon dioxide electrolysers10.1038/s41893-022-00879-8 ↗
10. Energy- and carbon-efficient CO2/CO electrolysis to multicarbon products via asymmetric ion migration–adsorption10.1038/s41560-022-01188-2 ↗
11. The effect of the tetraalkylammonium cation in the electrochemical CO2 reduction reaction on copper electrode10.1021/acscatal.4c02297 ↗
12. The electrical double layer and the theory of electrocapillarity10.1021/cr60130a002 ↗
13. On the importance of the electric double layer structure in aqueous electrocatalysis10.1038/s41467-021-27909-x ↗
14. Highly cooperative CO2 adsorption via a cation crowding mechanism on a cesium-exchanged phillipsite zeolite10.1002/anie.202305816 ↗
15. Influence of cations on HCOOH and CO formation during CO2 reduction on a PdMLPt(111) electrode10.1021/jacs.3c03786 ↗
16. Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium10.1038/s41929-022-00761-y ↗
17. Quantitative understanding of cation effects on the electrochemical reduction of CO2 and H+ in acidic solution10.1021/acscatal.2c04875 ↗
18. Mechanism of cations suppressing proton diffusion kinetics for electrocatalysis
19. Understanding and leveraging the effect of cations in the electrical double layer for electrochemical CO2 reduction
20. Atomic-scale understanding of alkali metal cation effects on electro-catalytic reactions
21. Surface-immobilized cross-linked cationic polyelectrolyte enables CO2 reduction with metal cation-free acidic electrolyte10.1038/s41467-023-41396-2 ↗
22. Uncovering the cation effects on the electroreduction of CO2 on Pd/C catalysts − an SEIRAS study10.1016/j.jcat.2024.115520 ↗
23. Molecular understanding of the critical role of alkali metal cations in initiating CO2 electroreduction on Cu(100) surface10.1038/s41467-024-44896-x ↗
24. A cation concentration gradient approach to tune the selectivity and activity of CO2 electroreduction10.1002/anie.202214173 ↗
25. Probing cation effects on ∗CO intermediates from electroreduction of CO2 through operando Raman spectroscopy10.1021/jacs.3c05799 ↗
26. Cation-dependent impact of CO2 on Cu-catalyzed electrochemical CO reduction reaction10.1021/acscatal.4c02498 ↗
27. Cation-induced interfacial hydrophobic microenvironment promotes the C-C coupling in electrochemical CO2 reduction10.1021/jacs.3c13602 ↗
28. Investigating the role of potassium cations during electrochemical CO2 reduction10.1039/D2NR03438G ↗
29. Cation effects on the adsorbed intermediates of CO2 electroreduction are systematic and predictable10.1021/acscatal.4c00727 ↗
30. Specific adsorption of alkaline cations enhances CO-CO coupling in CO2 electroreduction10.1021/jacs.4c10455 ↗
31. Exploring multivalent cations-based electrolytes for CO2 electroreduction10.1016/j.electacta.2021.139055 ↗
32. The role of cation acidity on the competition between hydrogen evolution and CO2 reduction on gold electrodes10.1021/jacs.1c10171 ↗
33. Influence of tetraethylammonium cation on electrochemical CO2 reduction over Cu, Ag, Ni, and Fe surfaces10.1016/j.jcat.2022.01.013 ↗
34. Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields10.1038/s41929-024-01278-2 ↗
35. How alkali cations affect salt precipitation and CO2 electrolysis performance in membrane electrode assembly electrolyzers10.1039/D2EE03725D ↗
36. Quantitative analysis and manipulation of alkali metal cations at the cathode surface in membrane electrode assembly electrolyzers for CO2 reduction reactions
37. Preventing salt formation in zero-gap CO2 electrolyzers by quantifying cation accumulation10.1021/acsenergylett.4c03242 ↗
38. Correlating hydration free energy and specific adsorption of alkali metal cations during CO2 electroreduction on Au10.1038/s41929-022-00816-0 ↗
39. Catalytic peculiarity of alkali metal cation-free electrode/polyelectrolyte interfaces toward CO2 reduction10.1021/jacs.4c04591 ↗
40. Interplay of local pH and cation hydrolysis during electrochemical CO2 reduction visualized by in operando chemical shift-resolved magnetic resonance imaging10.1021/acs.jpcc.3c03563 ↗
41. CO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment10.1038/s41467-022-35415-x ↗
42. Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media10.1038/s41929-024-01179-4 ↗
43. Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis10.1038/s41929-023-01003-5 ↗
44. Carbon- and energy-efficient ethanol electrosynthesis via interfacial cation enrichment10.1038/s44160-024-00662-x ↗
45. Immobilized tetraalkylammonium cations enable metal-free CO2 electroreduction in acid and pure water10.1002/anie.202317828 ↗
46. A solid-state electrolyte facilitates acidic CO2 electrolysis without alkali metal cations by regulating proton transport10.1021/jacs.4c11564 ↗
47. Selective and stable ethanol synthesis via electrochemical CO2 reduction in a solid electrolyte reactor10.1021/acsenergylett.4c03091 ↗
48. Weakly coordinating organic cations are intrinsically capable of supporting CO2 reduction catalysis10.1021/jacs.3c04769 ↗