journal article·2023-06Open access

Bridging fundamental science and applied science to accelerate CO2 electrolyzer scale-up

Maxwell Goldman, Aditya Prajapati, Eric Duoss, Sarah Baker, Christopher Hahn

Abstract

CO2 electrolysis coupled with renewable energy is an attractive option to decarbonize the chemical manufacturing sector. To accelerate the deployment of a commercially viable electrolyzer, there remains a need to de-risk scaling electrolyzers from the laboratory scale to industrially relevant conditions. An opportunity exists for the low-temperature CO2 electrolysis community can translate novel cell configurations and practices from adjacent fields to bridge the gap between fundamental sciences, and scaling a CO2 electrolyzer in geometric size, performance, and durability. Employing closed research loops that incorporate system-level analysis, continuum and atomistic modeling, and advanced characterization techniques can accelerate the rapid deployment of a CO2 electrolyzer.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Electrocatalysts for Energy Conversion · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. Rama
2. Climate change mitigation potential of carbon capture and utilization in the chemical industry10.1073/pnas.1821029116 ↗
3. Powering the future with liquid sunshine10.1016/j.joule.2018.08.016 ↗
4. Commercialization of CO2 electrolysis by haldor topsoe10.1149/MA2021-031191mtgabs ↗
5. Techno-economic assessment of low-temperature carbon dioxide electrolysis10.1038/s41893-021-00739-x ↗
6. Gas diffusion electrodes, reactor designs and key metrics of low-temperature CO2 electrolysers10.1038/s41560-021-00973-9 ↗
7. Single pass CO2 conversion exceeding 85% in the electrosynthesis of multicarbon products via local CO2 regeneration10.1021/acsenergylett.1c01122 ↗
8. Electrocatalytic CO2-to-C2+ with ampere-level current on heteroatom-engineered copper via tuning ∗CO intermediate coverage10.1021/jacs.2c06820 ↗
9. Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte10.1021/acs.chemrev.8b00705 ↗
10. Advances and challenges in electrochemical CO2 reduction processes: an engineering and design perspective looking beyond new catalyst materials10.1039/C9TA13298H ↗
11. Electrifying the production of sustainable aviation fuel: the risks, economics, and environmental benefits of emerging pathways including CO210.1039/D2EE02439J ↗
12. Environmental applications of electrochemical technology. What is needed to enable full-scale applications?10.1016/j.coelec.2019.07.002 ↗
13. How long does innovation and commercialisation in the energy sectors take? Historical case studies of the timescale from invention to widespread commercialisation in energy supply and end use technology10.1016/j.enpol.2018.08.061 ↗
14. Gas diffusion electrodes and membranes for CO2 reduction electrolysers10.1038/s41578-021-00356-2 ↗
15. CO2 reduction on gas-diffusion electrodes and why catalytic performance must Be assessed at commercially-relevant conditions10.1039/C8EE03134G ↗
16. How membrane characteristics influence the performance of CO2 and CO electrolysis10.1039/D2EE01818G ↗
17. Continuous carbon dioxide electroreduction to concentrated multi-carbon products using a membrane electrode assembly10.1016/j.joule.2019.07.021 ↗
18. H-cell vs gas diffusion electrolyzer for evaluating intrinsic activity of nanocatalysts for electrochemical CO2 reduction10.1149/MA2019-02/22/1072 ↗
19. Bridging knowledge gaps in liquid- and vapor-fed CO2 electrolysis through active electrode area
20. High-entropy alloys as catalysts for the CO2 and CO reduction reactions: experimental realization10.1021/acscatal.9b04302 ↗
21. Electrolyte competition controls surface binding of CO intermediates to CO2 reduction catalysts10.1021/acs.jpcc.1c04337 ↗
22. The priority and challenge of high-power performance of low-platinum proton-exchange membrane fuel cells10.1021/acs.jpclett.6b00216 ↗
23. Bridging the gap between highly active oxygen reduction reaction catalysts and effective catalyst layers for proton exchange membrane fuel cells10.1038/s41560-021-00824-7 ↗
24. Catalyst stability benchmarking for the oxygen evolution reaction: the importance of backing electrode material and dissolution in accelerated aging studies10.1002/cssc.201701523 ↗
25. Decoupling structure-sensitive deactivation mechanisms of Ir/IrOx electrocatalysts toward oxygen evolution reaction10.1016/j.jcat.2019.01.018 ↗
26. OER catalyst stability investigation using RDE technique: a stability measure or an artifact?10.1149/2.0301908jes ↗
27. Studying the oxygen reduction and hydrogen oxidation reactions under realistic fuel cell conditions10.1016/j.elecom.2008.09.001 ↗
28. Operando local PH measurement within gas diffusion electrodes performing electrochemical carbon dioxide reduction10.1021/acs.jpcc.1c06265 ↗
29. Quantification of water transport in a CO2 electrolyzer10.1039/D0EE02219E ↗
30. Cobalt oxide-based materials as non-PGM catalyst for HER in PEM electrolysis and in situ XAS characterization of its functional state
31. Influence of water vapor on the performance of Au/ZnO catalysts in methanol synthesis from CO2 and H2: a high-pressure kinetic and TAP reactor study10.1016/j.apcatb.2021.120416 ↗
32. Differential electrochemical mass spectrometer cell design for online quantification of products produced during electrochemical reduction of CO210.1021/acs.analchem.5b02080 ↗
33. Flow electrolyzer mass spectrometry with a gas-diffusion electrode design10.1002/anie.202013713 ↗
34. Interfacial analysis of a PEM electrolyzer using X-ray computed tomography10.1039/C9SE00364A ↗
35. Cracks as efficient tools to mitigate flooding in gas diffusion electrodes used for the electrochemical reduction of carbon dioxide10.1002/smtd.202200369 ↗
36. Conformal Cu coating on electrospun nanofibers for 3D electro-conductive networks10.1002/aelm.201900767 ↗
37. Progress and challenges on the thermal management of electrochemical energy conversion and storage technologies: fuel cells, electrolysers, and supercapacitors10.1016/j.pecs.2021.100966 ↗
38. Durable cathodes and electrolyzers for the efficient aqueous electrochemical reduction of CO210.1002/cssc.201902933 ↗
39. Effect of scaling-up on the performance and degradation of long-term operated electrolyte supported solid oxide cell, stack and module in electrolysis mode10.1016/j.jpowsour.2021.230346 ↗
40. A review of proton exchange membrane water electrolysis on degradation mechanisms and mitigation strategies10.1016/j.jpowsour.2017.09.006 ↗
41. System integration, durability and reliability of fuel cells: challenges and solutions10.1016/j.apenergy.2016.12.083 ↗
42. Durability testing of low-iridium PEM water electrolysis membrane electrode assemblies10.1149/1945-7111/ac6d14 ↗
43. Opus 12's CO2 transformation and the importance of collaboration10.1016/j.isci.2021.102677 ↗