Single versus poly-crystalline layered oxide cathode materials for solid-state battery applications - a short review article
Source abstract
Abstract
Abstract The recent achievements following the application of single-crystalline (SC) cathode material in solid-state batteries are discussed in this mini-review. The characteristics of SC and poly-crystalline (PC) cathode materials are explored, with emphasis on the kinetic and mechanical properties. The critical factors influencing their performance in liquid electrolyte and solid-state battery cells are investigated. Finally, the advantages and disadvantages of both morphologies are discussed and considerations to ensure a fair comparison between SC and PC cathodes in different systems are raised.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Thermal Expansion and Ionic Conductivity
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References (67)
Show source-provided references
1. The development and future of lithium ion batteries10.1149/2.0251701jes ↗
2. Current and future lithium-ion battery manufacturing10.1016/j.isci.2021.102332 ↗
3. The role of metal substitutions in the development of Li batteries, part I: cathodes10.1039/D1MA00081K ↗
4. A reflection on lithium-ion battery cathode chemistry10.1038/s41467-020-15355-0 ↗
5. Surface modification strategies for improving the cycling performance of Ni-rich cathode materials10.1002/ejic.202000408 ↗
6. A review on synthesis and engineering of crystal precursors produced via coprecipitation for multicomponent lithium-ion battery cathode materials10.1039/C9CE00679F ↗
7. Constant dripping wears away a stone: fatigue damage causing particles' cracking10.1016/j.jpowsour.2019.01.084 ↗
8. Rational design of quasi-zero-strain NCM cathode materials for minimizing volume change effects in all-solid-state batteries10.1021/acsmaterialslett.9b00441 ↗
9. A perspective on single-crystal layered oxide cathodes for lithium-ion batteries10.1016/j.ensm.2021.02.003 ↗
10. Single-crystal nickel-rich layered-oxide battery cathode materials: synthesis, electrochemistry, and intra-granular fracture10.1016/j.ensm.2020.01.027 ↗
11. Synthesis of Co-free Ni-rich single crystal positive electrode materials for lithium ion natteries: part I. two-step lithiation method for Al- or Mg-doped LiNiO210.1149/1945-7111/abf7e8 ↗
12. Shape-controlled synthesis of high tap density cathode oxides for lithium ion batteries10.1039/c2cp40209b ↗
13. Synthesis of single crystalline Ni-rich NMC811 cathode materials and improved performance enabled by ultrathin surface coating layer10.1149/MA2019-02/5/326 ↗
14. Single-crystal LiNi0.5Co0.2Mn0.3O2: a high thermal and cycling stable cathodes for lithium-ion batteries10.1007/s10853-019-04133-z ↗
15. A simple one-step molten salt method for synthesis of micron-sized single primary particle LiNi0.8Co0.1Mn0.1O2 cathode material for lithium-ion batteries10.1007/s11581-020-03500-0 ↗
16. Superiority of single-crystal to polycrystalline LiNixCoyMn1-x-yO2 cathode materials in storage behaviors for lithium-ion batteries10.1021/acssuschemeng.0c05011 ↗
17. Synthesis of single crystal LiNi0.88Co0.09Al0.03O2 with a two-step lithiation method10.1149/2.0681910jes ↗
18. Synthesis of single crystal LiNi0.6Mn0.2Co0.2O2 with enhanced electrochemical performance for lithium ion batteries10.1149/2.0951805jes ↗
19. Single-crystal LiNi0.6Co0.2Mn0.2O2 as high performance cathode materials for Li-ion batteries10.1016/j.jallcom.2016.03.061 ↗
20. Molybdate flux growth of idiomorphic Li(Ni1/3Co1/3Mn1/3)O2 single crystals and characterization of their capabilities as cathode materials for lithium-ion batteries10.1039/C6TA01593J ↗
21. High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes10.1038/s41560-020-0575-z ↗
22. Benchmarking the performance of all-solid-state lithium batteries10.1038/s41560-020-0565-1 ↗
23. Utmost limits of various solid electrolytes in all-solid-state lithium batteries: a critical review10.1016/j.rser.2019.04.035 ↗
24. Impact of protonation on the electrochemical performance of Li7La3Zr2O12 garnets10.1021/acsami.0c23144 ↗
25. Challenges and perspectives of garnet solid electrolytes for all solid-state lithium batteries10.1016/j.jpowsour.2018.04.019 ↗
26. Review on polymer-based composite electrolytes for lithium batteries10.3389/fchem.2019.00522 ↗
27. The role of polymers in lithium solid-state batteries with inorganic solid electrolytes10.1039/D1TA02796D ↗
28. Nido-borate/closo-borate mixed-anion electrolytes for all-solid-state batteries10.1021/acs.chemmater.9b03933 ↗
29. Status and prospects of hydroborate electrolytes for all-solid-state batteries10.1016/j.ensm.2019.08.032 ↗
30. 4 V room-temperature all-solid-state sodium battery enabled by a passivating cathode/hydroborate solid electrolyte interface10.1039/D0EE01569E ↗
31. Closo-hydroborate sodium salts as an emerging class of room-temperature solid electrolytes10.1016/j.xcrp.2020.100217 ↗
32. Nido-hydroborate-based electrolytes for all-solid-state lithium batteries10.1002/adfm.202010046 ↗
33. Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries10.1039/C9EE03828K ↗
34. Lithium ytterbium-based halide solid electrolytes for high voltage all-solid-state batteries10.1021/acsmaterialslett.1c00142 ↗
35. Lithium-metal anode instability of the superionic halide solid electrolytes and the implications for solid-state batteries10.1002/ange.202015238 ↗
36. Sulfide-based solid-state electrolytes: synthesis, stability, and potential for all-solid-state batteries10.1002/adma.201901131 ↗
37. Electrochemo-mechanical effects on structural integrity of Ni-rich cathodes with different microstructures in all solid-state batteries10.1002/aenm.202003583 ↗
38. High energy density single-crystal NMC/Li6PS5Cl cathodes for all-solid-state lithium metal batteries10.1021/acsami.1c07952 ↗
39. There and back again—the journey of LiNiO2 as a cathode active material10.1002/anie.201812472 ↗
40. Atomistic understanding of the LiNiO2-NiO2 phase diagram from experimentally guided lattice models10.1039/D1TA00563D ↗
41. Phase transformation behavior and stability of LiNiO2 cathode material for Li-ion batteries obtained from in situ gas analysis and operando X-ray diffraction10.1002/cssc.201900032 ↗
42. Editors' choice—quantification of the impact of chemo-mechanical degradation on the performance and cycling stability of NCM-based cathodes in solid-state Li-ion batteries10.1149/1945-7111/ac13d2 ↗
43. Single- or poly-crystalline Ni-rich layered cathode, sulfide or halide solid electrolyte: which will be the winners for all-solid-state batteries?10.1002/aenm.202100126 ↗
44. Origin of outstanding stability in the lithium solid electrolyte materials: insights from thermodynamic analyses based on first-principles calculations10.1021/acsami.5b07517 ↗
45. Material design strategy for halide solid electrolytes Li3MX6 (X = Cl, Br, and I) for all-solid-state high-voltage Li-ion batteries10.1021/acs.chemmater.1c00555 ↗
46. Capacity fading mechanisms in Ni-rich single-crystal NCM cathodes10.1021/acsenergylett.1c01089 ↗
47. Prospects and limitations of single-crystal cathode materials to overcome cross-talk phenomena in high-voltage lithium ion cells10.1039/D0TA11775G ↗
48. Polycrystalline and single crystalline NCM cathode materials—quantifying particle cracking, active surface area, and lithium diffusion10.1002/aenm.202003400 ↗
49. Single crystal cathodes enabling high-performance all-solid-state lithium-ion batteries10.1016/j.ensm.2020.05.007 ↗
50. Synthesis and postprocessing of single-crystalline LiNi0.8Co0.15Al0.05O2 for solid-state lithium-ion batteries with high capacity and long cycling stability10.1021/acs.chemmater.1c00471 ↗
51. Impact of cathode material particle size on the capacity of bulk-type all-solid-state batteries10.1021/acsenergylett.8b00275 ↗
52. High active material loading in all-solid-state battery electrode via particle size optimization10.1002/aenm.201902881 ↗
53. Electrochemical properties of composite cathode using bimodal sized electrolyte for all-solid-state batteries10.1149/2.0481903jes ↗
54. Editors' choice—washing of nickel-rich cathode materials for lithium-ion batteries: towards a mechanistic understanding10.1149/2.1351915jes ↗
55. Surface regulation enables high stability of single-crystal lithium-ion cathodes at high voltage10.1038/s41467-020-16824-2 ↗
56. Stable thiophosphate-based all-solid-state lithium batteries through conformally interfacial nanocoating10.1021/acs.nanolett.9b02678 ↗
57. Self-stabilized LiNi0.8Mn0.1Co0.1O2 in thiophosphate-based all-solid-state batteries through extra LiOH10.1016/j.ensm.2021.06.024 ↗
58. High performance all-solid-state batteries with a Ni-rich NCM cathode coated by atomic layer deposition and lithium thiophosphate solid electrolyte10.1021/acsaem.1c01487 ↗
59. Building ultraconformal protective layers on both secondary and primary particles of layered lithium transition metal oxide cathodes10.1038/s41560-019-0387-1 ↗
60. Reactive boride infusion stabilizes Ni-rich cathodes for lithium-ion batteries10.1038/s41560-021-00782-0 ↗
61. On the functionality of coatings for cathode active materials in thiophosphate-based all-solid-state batteries10.1002/aenm.201900626 ↗
62. Effect of surface carbonates on the cyclability of LiNbO3-coated NCM622 in all-solid-state batteries with lithium thiophosphate electrolytes10.1038/s41598-021-84799-1 ↗
63. Stabilizing effect of a hybrid surface coating on a Ni-rich NCM cathode material in all-solid-state batteries10.1021/acs.chemmater.9b02947 ↗
64. Excellent performance single-crystal NCM cathode under high mass loading for all-solid-state lithium batteries10.1016/j.electacta.2020.137185 ↗
65. Deciphering interfacial chemical and electrochemical reactions of sulfide-based all-solid-state batteries10.1002/aenm.202100210 ↗
66. New cost-effective halide solid electrolytes for all-solid-state batteries: mechanochemically prepared Fe3+-substituted Li2ZrCl610.1002/aenm.202003190 ↗
67. High cathode utilization efficiency through interface engineering in all-solid-state lithium-metal batteries10.1039/C9TA09935B ↗