journal article·2025-11

Non‐Metallic Element Modification: A Promising Strategy Toward Efficient Electrocatalytic CO 2 Reduction

Junjie Ding, Jiaqi Wu, Weiling Hu, Yang Wang, Youyu Duan, Lu Xia, Danmei Yu, Xiaoping Tao, Liyong Gan, Xiaoyuan Zhou

Advanced Functional Materials· Volume 35· Issue 47
Publisher page

Abstract

Abstract Electrocatalytic carbon dioxide reduction reaction (CO 2 RR), driven by renewable electrical energy, presents as a promising technology for converting CO 2 into valuable chemicals and fuels, thereby contributing to the establishment of a sustainable energy society. Metal catalysts play a pivotal role in CO 2 RR, but often encounter issues with insufficient activity, poor selectivity, and inadequate stability. Recently, extensive researches has demonstrated that the modification of using cost‐effective and easily accessible non‐metallic elements can significantly enhance the CO 2 RR performance, exhibiting great application potential. In this review, we will conduct a thorough analysis of non‐metallic element modified metal catalysts (NM‐MCs) toward CO 2 RR, including reaction mechanisms, synthesis methods, and optimization strategies. Besides, we delve into the latest advancements and challenges in the implementation of NM‐MCs in typical CO 2 RR devices, such as flow cells, membrane electrode assemblies, and solid‐state electrolyte reactors. Finally, future research opportunities are discussed aimed at advancing the industrial implementation of NM‐MCs in CO 2 RR.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Electrocatalysts for Energy Conversion · Ammonia Synthesis and Nitrogen Reduction

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Physics and Center of Quantum Materials and Devices Chongqing University Chongqing 401331 P. R. China

College of Chemistry and Chemical Engineering Southwest University Chongqing 400715 P. R. China

School of Optoelectronic Engineering Chongqing University of Posts and Telecommunications Chongqing 400065 P. R. China

Mechanical Engineering RWTH Aachen University 52062 Aachen Germany

School of Chemistry and Chemical Engineering Chongqing University Chongqing 401331 P. R. China

Chongqing Institute of New Energy Storage Material and Equipment Chongqing 401120 P. R. China

State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing University Chongqing 401331 P. R. China

Funding

National Key Research and Development Program of China · National Natural Science Foundation of China · Fundamental Research Funds for the Central Universities · National Science Fund for Distinguished Young Scholars

References (100+)

Show source-provided references
1. 10.1126/science.aav350610.1126/science.aav3506 ↗
2. 10.1126/science.118856610.1126/science.1188566 ↗
3. 10.1126/science.aac472210.1126/science.aac4722 ↗
4. 10.1038/s41929-021-00694-y10.1038/s41929-021-00694-y ↗
5. 10.1038/nmat483410.1038/nmat4834 ↗
6. 10.1039/D3EE00964E10.1039/D3EE00964E ↗
7. 10.1002/adma.20210409010.1002/adma.202104090 ↗
8. 10.1038/s41557-021-00734-x10.1038/s41557-021-00734-x ↗
9. 10.1002/anie.20231762810.1002/anie.202317628 ↗
10. 10.1002/smll.20220765010.1002/smll.202207650 ↗
11. 10.1021/jacs.1c1221210.1021/jacs.1c12212 ↗
12. 10.1002/adfm.20220367710.1002/adfm.202203677 ↗
13. 10.1038/s41467-022-29698-310.1038/s41467-022-29698-3 ↗
14. 10.1016/j.joule.2021.04.01810.1016/j.joule.2021.04.018 ↗
15. 10.1002/advs.20210529210.1002/advs.202105292 ↗
16. 10.1002/anie.20220003910.1002/anie.202200039 ↗
17. 10.1002/anie.20231364610.1002/anie.202313646 ↗
18. 10.1002/ange.20220962910.1002/ange.202209629 ↗
19. 10.1002/anie.20200484610.1002/anie.202004846 ↗
20. 10.1038/s41560-021-00967-710.1038/s41560-021-00967-7 ↗
21. 10.1021/acsenergylett.1c0072310.1021/acsenergylett.1c00723 ↗
22. 10.1016/j.enchem.2023.10011110.1016/j.enchem.2023.100111 ↗
23. 10.1016/j.cclet.2021.12.01810.1016/j.cclet.2021.12.018 ↗
24. 10.1016/j.jechem.2022.03.04110.1016/j.jechem.2022.03.041 ↗
25. 10.1021/acsnano.0c1069710.1021/acsnano.0c10697 ↗
26. 10.1016/j.nanoen.2019.10438410.1016/j.nanoen.2019.104384 ↗
27. 10.1021/acs.nanolett.1c0438210.1021/acs.nanolett.1c04382 ↗
28. 10.1039/D1GC04146K10.1039/D1GC04146K ↗
29. 10.1016/j.checat.2022.05.01510.1016/j.checat.2022.05.015 ↗
30. 10.1002/anie.20220149110.1002/anie.202201491 ↗
31. 10.1038/s41586-022-05540-010.1038/s41586-022-05540-0 ↗
32. 10.1038/s41467-023-36261-110.1038/s41467-023-36261-1 ↗
33. 10.1039/C5SC03291A10.1039/C5SC03291A ↗
34. 10.1038/s41467-022-30733-610.1038/s41467-022-30733-6 ↗
35. 10.1038/s41467-019-08805-x10.1038/s41467-019-08805-x ↗
36. 10.1016/j.apcatb.2021.12093610.1016/j.apcatb.2021.120936 ↗
37. 10.1038/s41467-021-24936-610.1038/s41467-021-24936-6 ↗
38. 10.1002/adma.20200837310.1002/adma.202008373 ↗
39. 10.1039/D1EE01495A10.1039/D1EE01495A ↗
40. 10.1039/D4EE01325E10.1039/D4EE01325E ↗
41. 10.3390/ma1710241910.3390/ma17102419 ↗
42. 10.1002/anie.20221117410.1002/anie.202211174 ↗
43. 10.1002/anie.20221826910.1002/anie.202218269 ↗
44. 10.1007/s40820-019-0293-x10.1007/s40820-019-0293-x ↗
45. 10.1016/S1872-5805(22)60592-410.1016/S1872-5805(22)60592-4 ↗
46. 10.1021/acs.chemrev.2c0051410.1021/acs.chemrev.2c00514 ↗
47. 10.1038/s41560-019-0450-y10.1038/s41560-019-0450-y ↗
48. 10.1021/acscatal.2c0175010.1021/acscatal.2c01750 ↗
49. 10.1002/anie.20210957910.1002/anie.202109579 ↗
50. 10.1002/advs.20210288610.1002/advs.202102886 ↗
51. 10.1016/j.jechem.2022.03.03210.1016/j.jechem.2022.03.032 ↗
52. 10.1016/j.nanoen.2024.10994510.1016/j.nanoen.2024.109945 ↗
53. 10.1021/acsengineeringau.3c0003010.1021/acsengineeringau.3c00030 ↗
54. 10.26599/NRE.2022.912002110.26599/NRE.2022.9120021 ↗
55. 10.1002/smll.20210745010.1002/smll.202107450 ↗
56. 10.1021/acscatal.2c0154410.1021/acscatal.2c01544 ↗
57. 10.1016/j.scib.2022.04.00410.1016/j.scib.2022.04.004 ↗
58. 10.1002/adma.20210174110.1002/adma.202101741 ↗
59. 10.1038/s41467-020-20004-710.1038/s41467-020-20004-7 ↗
60. Zhao R. B. · Adv. Funct. Mater. · 2021 · 31 · 35
61. 10.1021/ja505791r10.1021/ja505791r ↗
62. 10.1021/acs.nanolett.2c0094510.1021/acs.nanolett.2c00945 ↗
63. 10.1038/s41929-020-00547-010.1038/s41929-020-00547-0 ↗
64. 10.1021/jacs.0c0642010.1021/jacs.0c06420 ↗
65. 10.1021/jacs.2c1338410.1021/jacs.2c13384 ↗
66. 10.1002/anie.20200878710.1002/anie.202008787 ↗
67. 10.1039/D0NR03044A10.1039/D0NR03044A ↗
68. 10.1002/adma.20170628710.1002/adma.201706287 ↗
69. 10.1002/ange.20191271910.1002/ange.201912719 ↗
70. 10.1002/anie.20190607910.1002/anie.201906079 ↗
71. 10.1021/jacs.8b0081410.1021/jacs.8b00814 ↗
72. 10.1002/anie.20191497710.1002/anie.201914977 ↗
73. 10.1002/smll.20190366810.1002/smll.201903668 ↗
74. 10.1016/j.apcatb.2020.11863010.1016/j.apcatb.2020.118630 ↗
75. 10.1021/jacs.0c0222910.1021/jacs.0c02229 ↗
76. 10.1016/j.apcatb.2020.11959110.1016/j.apcatb.2020.119591 ↗
77. 10.1002/anie.20221232910.1002/anie.202212329 ↗
78. 10.1002/anie.20190157510.1002/anie.201901575 ↗
79. 10.1002/anie.20181017510.1002/anie.201810175 ↗
80. 10.1002/anie.20191497710.1002/anie.201914977 ↗
81. 10.1021/jacs.7b0273610.1021/jacs.7b02736 ↗
82. 10.1021/acsnano.1c0085810.1021/acsnano.1c00858 ↗
83. 10.1021/acscatal.2c0180510.1021/acscatal.2c01805 ↗
84. 10.1016/j.seppur.2024.12914710.1016/j.seppur.2024.129147 ↗
85. 10.1021/acsanm.0c0336110.1021/acsanm.0c03361 ↗
86. 10.1002/adfm.20231198910.1002/adfm.202311989 ↗
87. 10.1016/j.ijoes.2023.10042710.1016/j.ijoes.2023.100427 ↗
88. 10.1016/j.cej.2023.14360610.1016/j.cej.2023.143606 ↗
89. 10.1016/j.jes.2024.03.01210.1016/j.jes.2024.03.012 ↗
90. Xu W. · Fuel Process. Technol. · 2023 · 250
91. 10.1016/j.jechem.2017.08.01010.1016/j.jechem.2017.08.010 ↗
92. 10.1016/j.apcatb.2022.12119110.1016/j.apcatb.2022.121191 ↗
93. 10.1038/s41467-021-24105-910.1038/s41467-021-24105-9 ↗
94. 10.1016/j.elecom.2019.05.02010.1016/j.elecom.2019.05.020 ↗
95. 10.1039/C8CY00912K10.1039/C8CY00912K ↗
96. 10.1021/acsanm.8b0120610.1021/acsanm.8b01206 ↗
97. 10.1016/j.xcrp.2023.10129410.1016/j.xcrp.2023.101294 ↗
98. 10.1021/acscatal.2c0261710.1021/acscatal.2c02617 ↗
99. 10.1002/adfm.20240897710.1002/adfm.202408977 ↗
100. 10.1007/s12274-023-6247-010.1007/s12274-023-6247-0 ↗