journal article·2022-06

Hydrogen evolution reaction on Pt and Ru in alkali with volmer-step promotors and electronic structure modulators

Sengeni Anantharaj

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Abstract

Alkaline water electrolysis despite having a variety of choices for anodic oxygen evolution reaction (OER) catalysts out of non-precious metals suffers significantly due to the poor kinetics of cathodic hydrogen evolution reaction (HER) even with the state-of-the-art Pt and equally active Ru. The Volmer-step (water dissociation (WD) coupled proton adsorption) of alkaline HER is mostly the rate-determining step (RDS) and costs most of the work required. In this review, recent developments in improving the HER kinetics of Pt and Ru with Volmer-step promotors and electronic structure modulators have been comprehensively analyzed and critically presented with the challenges and prospects.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Advanced battery technologies research

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