Integrated Textile Supercapacitors Enhanced with Energy‐Absorbing Spacer Fabrics and Ti₃C₂T_x MXene

Abstract The rapid development of wearable electronics requires energy storage devices capable of withstanding both static and dynamic deformations. The versatility of textile supercapacitors renders them promising candidates, but their low electrochemical performance especially under mechanical deformation, poses many limitations for practical use. In this study, MXene‐based textile supercapacitors are designed and fabricated using hierarchical spacer fabrics as the skeleton to provide robust mechanical support and stable performance. Ti₃C₂T_x MXene is adopted as the current collector and active material for the spacer fabric supercapacitor, resulting in an impressive areal capacitance of 415 mF cm⁻² with a MXene loading of 4.2 mg cm⁻². Remarkable stability and durability are achieved in the form of three‐dimensional (3D) textile supercapacitors, even under both static and dynamic deformations. The compressive behaviors of these supercapacitors can be easily adjusted (e.g., from 10 to 168 KPa at 50% compression) by altering the spacer fabric structure, demonstrating their energy‐absorption (damping of kinetic energy) capability and their potential to meet the requirements of various wearable applications.