A critical review on the electrochemical production and use of peroxo-compounds
Source abstract
Abstract
Abstract Peroxosulfates, peroxocarbonates and peroxophosphates form a group of powerful oxidants that can be synthesized electrochemically and used for the treatment of refractory compounds. Based on the latest studies in the bibliography, this critical review presents the potentialities and also the current limits of the electrosynthesis of these peroxo compounds coupled to their reactions with target compounds. The main parameters such as electrode material, use of additives, cell geometry, temperature and pH affecting the efficiency of the process will be discussed. To conclude, the new challenges and research perspectives in this theme to be performed will be presented before development at an industrial scale.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced oxidation water treatment · Advanced Photocatalysis Techniques · Electrocatalysts for Energy Conversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (49)
Show source-provided references
1. Electrochemical oxidation of organic pollutants for wastewater treatment10.1016/j.coelec.2018.07.010 ↗
2. Electrochemical advanced oxidation processes: a review on their application to synthetic and real wastewaters10.1016/j.apcatb.2016.08.037 ↗
3. Electrocoagulation and advanced electrocoagulation processes: a general review about the fundamentals, emerging applications and its association with other technologies10.1016/j.jelechem.2017.07.047 ↗
4. Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅ OH/⋅ O− in aqueous solution10.1063/1.555805 ↗
5. Role of hydroxyl radicals during the competitive electrooxidation of organic compounds on a boron-doped diamond anode10.1007/s12678-013-0150-5 ↗
6. The chemistry of persulfate. I. The kinetics and mechanism of the decomposition of the persulfate ion in aqueous medium10.1021/ja01151a024 ↗
7. Sulfate radical and its application in decontamination technologies10.1080/10643389.2014.970681 ↗
8. Electrochemical oxidation of organics in sulfate solutions on boron-doped diamond electrode: multiple pathways for sulfate radical generation10.1016/j.apcatb.2019.04.060 ↗
9. Challenges and opportunities in the removal of sulphate ions in contaminated mine water: a review10.1016/j.mineng.2017.12.004 ↗
10. Treatment of industrial wastewater produced by desulfurization process in a coal-fired power plant via FO-MD hybrid process10.1016/j.chemosphere.2018.06.180 ↗
11. Rate constants and mechanism of reaction of sulfate radical anion with aromatic compounds10.1021/ja00443a030 ↗
12. Effect of current density and sulfuric acid concentration on persulfuric acid generation by boron-doped diamond film anodes10.1007/s10800-014-0692-0 ↗
13. A rapid spectrophotometric determination of persulfate anion in ISCO10.1016/j.chemosphere.2008.08.043 ↗
14. Radimer · 1979
15. Studien über die Bildung von Überschwefelsäure10.1002/bbpc.18950021202 ↗
16. The mechanism of the anodic formation of the peroxodisulphate ion on platinum–IV. influence of alkali-metal cations10.1016/0013-4686(71)85123-X ↗
17. Electrochemical generation of persulfate and its performance on 4-bromophenol treatment10.1016/j.seppur.2018.06.071 ↗
18. Cathodic indirect oxidation of organic pollutant paired to anodic persulfate production10.1016/j.jelechem.2017.03.040 ↗
19. Degradation of ronidazole by electrochemically simultaneously generated persulfate and ferrous ions10.1016/j.chemosphere.2019.124579 ↗
20. Experimental study on four cation exchange membranes in electrosynthesis of ammonium persulfate10.33961/JECST.2018.9.1.37 ↗
21. Electrochemical preparation of peroxodisulfuric acid using boron doped diamond thin film electrodes10.1016/S0013-4686(02)00688-6 ↗
22. Understanding persulfate production at boron doped diamond film anodes10.1016/j.electacta.2014.10.104 ↗
23. Indirect electrochemical oxidation of 2, 4-dichlorophenoxyacetic acid using electrochemically-generated persulfate10.1016/j.chemosphere.2018.04.004 ↗
24. Toward a green generation of oxidant on demand: practical electrosynthesis of ammonium persulfate10.1021/acssuschemeng.5b01372 ↗
25. Can the substrate of the diamond anodes influence on the performance of the electrosynthesis of oxidants ?10.1016/j.jelechem.2019.113416 ↗
26. Understanding the electrolytic generation of sulfate and chlorine oxidative species with different boron-doped diamond anodes10.1016/j.jelechem.2019.113756 ↗
27. Electrochemical peroxodisulfate (PDS) generation on a self-doped TiO2 nanotube Array electrode10.1021/acs.iecr.8b01208 ↗
28. ISCO technology overview: do you really understand the chemistry?
29. Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants10.1016/j.cej.2017.11.059 ↗
30. Chapter 6 - indirect electrochemical oxidation using hydroxyl radical, active chlorine, and peroxodisulfate10.1016/B978-0-12-813160-2.00006-7 ↗
31. Electrolysis assisted persulfate with annular iron sheet as anode for the enhanced degradation of 2, 4-dinitrophenol in aqueous solution10.1016/j.jhazmat.2017.11.007 ↗
32. Iron electrode as efficient persulfate activator for oxcarbazepine degradation: performance, mechanism, and kinetic modeling10.1016/j.seppur.2017.01.007 ↗
33. Improving the catalytic effect of peroxodisulfate and peroxodiphosphate electrochemically generated at diamond electrode by activation with light irradiation10.1016/j.chemosphere.2018.05.121 ↗
34. Removal of 2-MIB and geosmin by electrogenerated persulfate: performance, mechanism and pathways10.1016/j.chemosphere.2016.11.134 ↗
35. Degradation of chloramphenicol using a combination system of simulated solar light, Fe2+ and persulfate10.1016/j.cej.2018.04.124 ↗
36. Degradation and mechanism of 2, 4-dichlorophenoxyacetic acid (2, 4-D) by thermally activated persulfate oxidation10.1016/j.chemosphere.2018.08.127 ↗
37. Electrochemical synthesis of sodium peroxycarbonate at boron-doped diamond electrodes10.1149/1.1576050 ↗
38. Efficient electrochemical production of peroxodicarbonate applying DIACHEM® diamond electrodes
39. Conversion of carbon dioxide to peroxycarbonate at boron-doped diamond electrode10.1016/j.elecom.2003.11.014 ↗
40. Percarbonate mediated advanced oxidation completely degrades recalcitrant pesticide imidacloprid: role of reactive oxygen species and transformation products10.1016/j.seppur.2020.117269 ↗
41. Percarbonate oxidation of landfill leachates towards removal of ultraviolet quenchers
42. On the applications of peroxodiphosphate produced by BDD-electrolyses10.1016/j.cej.2013.08.022 ↗
43. Othmer · 1996 · vol. 18 · 202
44. A new method for the preparation of peroxymonophosphoric acid10.1139/v03-010 ↗
45. A new method for the preparation of permonophosphoric acid10.1021/ja01282a037 ↗
46. Electrochemical synthesis of peroxomonophosphate using boron-doped diamond anodes10.1007/s10800-007-9405-2 ↗
47. Kinetic investigation of the oxidation of N-alkyl anilines by peroxomonophosphoric acid in anionic surfactant sodium lauryl sulphate
48. Electrochemical synthesis of peroxodiphosphate using boron-doped diamond anodes10.1149/1.2039936 ↗
49. In situ electrochemically generated peroxymonophosphoric acid as an oxidant for the effective removal of gaseous acetaldehyde10.1016/j.cej.2017.05.068 ↗